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- W2047492204 abstract "This paper reports the thermal conversion of the tetrahydrothiophene (THT)-precursor to poly(p-phenylene vinylene) (PPV). Detailed investigations of the conversion process show that the leaving groups THT and HCl do not eliminate simultaneously. Moderate temperatures (≤125 °C) are sufficient to eliminate the THT while a higher temperature of ≈150 °C is necessary for the leaving group HCl. Furthermore, the THT groups split off at two characteristic temperatures. Our investigations have shown that a consistent picture of the reaction mechanism can only be obtained if the configuration of the polymer chain is considered. For the total reaction of the THT-precursor to PPV a reaction mechanism is suggested that consists of at least four steps. Copyright © 1999 John Wiley & Sons, Ltd." @default.
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- W2047492204 date "1999-05-01" @default.
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- W2047492204 title "The thermal conversion of the tetrahydrothiophene-precursor polymer to poly(p-phenylene vinylene)" @default.
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- W2047492204 doi "https://doi.org/10.1002/(sici)1099-1581(199905)10:5<251::aid-pat868>3.0.co;2-y" @default.
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