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- W2047520439 abstract "The use of mass spectra generated at 70 eV in electron ionization (EI) as a universal standard for EI has helped in the generation of searchable library databases and had a profound influence on the analytical applications of gas chromatography/mass spectrometry (GC/MS), similarly for liquid chromatography tandem mass spectrometry (LC−MS/MS), suggesting a novel method to normalize the collisional energy for the universalization of fragmentation energy for the analysis of Chemical Weapon Convention (CWC)-related chemicals by atmospheric pressure ionization-tandem mass spectrometry (API-MSn) using three-dimensional (3D) ion trap instruments. For normalizing fragmentation energy a “fragmentation energy index” (FEI) is proposed which is an arbitrary scale based on the fact of specific MS/MS fragmentation obtained at different collisional energies for the reference chemicals which are not CWC scheduled compounds. FEI 6 for the generation of an MSn library-searchable mass spectral database is recommended." @default.
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- W2047520439 date "2009-03-10" @default.
- W2047520439 modified "2023-10-15" @default.
- W2047520439 title "Fragmentation Energy Index for Universalization of Fragmentation Energy in Ion Trap Mass Spectrometers for the Analysis of Chemical Weapon Convention Related Chemicals by Atmospheric Pressure Ionization-Tandem Mass Spectrometry Analysis" @default.
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- W2047520439 doi "https://doi.org/10.1021/ac802079w" @default.
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