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- W2047559982 abstract "The morphology and phase properties of myristyl alcohol monolayers are studied using a Langmuir film balance and a Brewster angle microscope. The hysteresis in the compression/decompression π-A cycle corresponds to differences in the morphological patterns which evolve during compression and decompression. Circular condensed-phase domains are formed in the plateau region of the isotherm during the phase transition from a low-density fluid phase to the condensed phase on compression. This structure can be re-formed by decompression of the monolayer to π⩽22.5 mN m−1 at 25°C. However, if the monolayers are compressed to higher surface pressures and then decompressed, holes of the low-density fluid phase are formed in the continuous condensed phase, and foam-like patterns, consisting of these two phases evolve in the plateau region of the isotherm. This indicates a phase transition to a non-tilted phase during compression at π=22.5 mN m−1. The foam is metastable in the plateau region, and unstable at lower surface pressures. The morphological patterns of the circular condensed-phase domains, formed in the surrounding low-density fluid phase, are compared with patterns of the continuous condensed phase which contain holes of the low-density fluid phase. The dynamics of two-dimensional foam rupture are presented. The change in the contours of a ruptured lamella of the condensed phase can be demonstrated." @default.
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- W2047559982 title "Foam-like patterns in myristyl alcohol monolayers" @default.
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- W2047559982 doi "https://doi.org/10.1016/0927-7757(96)03588-1" @default.
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