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- W2047564304 abstract "The title compound, [Cd(S2O3)(C16H16N2)(H2O)]n, presents a polymeric one-dimensional structure running along the P21/c glide direction, with elementary units defined by six-coordinate CdII atoms bonded to three symmetry-related thiosulfate groups, a bidentate tetramethylphenanthroline ligand and one aqua ligand. The bridging thiosulfates bind metal centers through two different sequences, viz. Cd—S—Cd′ and Cd′—S′—S′—O′—Cd, defining a closed six-membered ring. Individual chains are held together via π–π interactions to generate two-dimensional networks parallel to the (100) plane. These, in turn, are connected by much weaker van der Waals interactions." @default.
- W2047564304 created "2016-06-24" @default.
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- W2047564304 date "2005-10-22" @default.
- W2047564304 modified "2023-10-14" @default.
- W2047564304 title "<i>catena</i>-Poly[[aqua(3,4,7,8-tetramethyl-1,10-phenanthroline-κ<sup>2</sup><i>N</i>,<i>N</i>′)cadmium(II)]-μ<sub>3</sub>-thiosulfato-κ<sup>3</sup><i>S</i>:<i>S</i>:<i>O</i>]" @default.
- W2047564304 cites W1723927677 @default.
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- W2047564304 doi "https://doi.org/10.1107/s0108270105025151" @default.
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