FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047564942> ?p ?o ?g. }

• W2047564942 endingPage "2390" @default.
• W2047564942 startingPage "2381" @default.
• W2047564942 abstract "A series of new dioxouranium(VI) complexes has been synthesised using N-(salicylidene)-L-histidine (H2sal-Lhis) and N-(o-vanillylidene)-L-histidine (H2van-L-his) and the corresponding D-histidines. They have been characterized by elemental analyses and physicochemical studies. The crystal and molecular structures of [UO2(van-L-his)(bipy)]·MeOH·H2O (bipy = 2,2′-bipyridine) have been determined by X-ray crystallography. The aldimine ligand in this compound is tridentate. The methanol and water molecules are hydrogen bonded to each other and the water molecule to the carboxylate O atom. The diamagnetic UO22+ entity serves as a chiroptical probe, undergoing stereospecific complex formation with the aldimine ligands. as well as for the interpretation of their 1H NMR spectra, which in conjunction with two-dimensional NMR spectra, reveal the different spin-spin interactions, including the long range one between the azomethine (CHN) and Hα proton of the amino acid residue. The CD and NMR spectral data of the quasi-enantiomorphous UO22+ complexes containing the L-/D-amino acid residues have helped to ascertain the conformational differences between each such pair; these differences can modulate energies of the half-filled highest occupied molecular orbitals in different ways. As these orbitals are involved in the electron-transfer process, the relevant complexes respond differently when subjected to cyclic voltammetry." @default.
• W2047564942 created "2016-06-24" @default.
• W2047564942 creator A5033880113 @default.
• W2047564942 creator A5040403502 @default.
• W2047564942 creator A5065499336 @default.
• W2047564942 date "1994-01-01" @default.
• W2047564942 modified "2023-09-27" @default.
• W2047564942 title "Synthesis, chiroptical and electrochemical studies of dioxouranium(<scp>VI</scp>) complexes of aldimine derivatives of<scp>L</scp>-/<scp>D</scp>-histidine and crystal structure of (2,2′-bipyridyl)dioxo(N-o-vanillylidene-<scp>L</scp>-histidinato)uranium(<scp>VI</scp>)–water–methanol(1/1/1)" @default.
• W2047564942 cites W1560694348 @default.
• W2047564942 cites W1593257054 @default.
• W2047564942 cites W1984377463 @default.
• W2047564942 cites W1987928326 @default.
• W2047564942 cites W1991197320 @default.
• W2047564942 cites W1999808657 @default.
• W2047564942 cites W2009017967 @default.
• W2047564942 cites W2020652769 @default.
• W2047564942 cites W2026047984 @default.
• W2047564942 cites W2026228805 @default.
• W2047564942 cites W2032875965 @default.
• W2047564942 cites W2033801331 @default.
• W2047564942 cites W2038040294 @default.
• W2047564942 cites W2049850818 @default.
• W2047564942 cites W2052343460 @default.
• W2047564942 cites W2053535968 @default.
• W2047564942 cites W2055162754 @default.
• W2047564942 cites W2058283422 @default.
• W2047564942 cites W2060177102 @default.
• W2047564942 cites W2061895360 @default.
• W2047564942 cites W2062290179 @default.
• W2047564942 cites W2062999257 @default.
• W2047564942 cites W2066365709 @default.
• W2047564942 cites W2068625088 @default.
• W2047564942 cites W2073614125 @default.
• W2047564942 cites W2074567491 @default.
• W2047564942 cites W2085557558 @default.
• W2047564942 cites W2085623177 @default.
• W2047564942 cites W2090897263 @default.
• W2047564942 cites W2091578514 @default.
• W2047564942 cites W2094947970 @default.
• W2047564942 cites W2118613516 @default.
• W2047564942 cites W2147739067 @default.
• W2047564942 cites W2148066840 @default.
• W2047564942 cites W2156318390 @default.
• W2047564942 cites W2160225272 @default.
• W2047564942 cites W2950322598 @default.
• W2047564942 cites W2953127493 @default.
• W2047564942 cites W312062007 @default.
• W2047564942 cites W3172375986 @default.
• W2047564942 cites W2070887621 @default.
• W2047564942 doi "https://doi.org/10.1039/dt9940002381" @default.
• W2047564942 hasPublicationYear "1994" @default.
• W2047564942 type Work @default.
• W2047564942 sameAs 2047564942 @default.
• W2047564942 citedByCount "10" @default.
• W2047564942 countsByYear W20475649422012 @default.
• W2047564942 countsByYear W20475649422014 @default.
• W2047564942 countsByYear W20475649422018 @default.
• W2047564942 crossrefType "journal-article" @default.
• W2047564942 hasAuthorship W2047564942A5033880113 @default.
• W2047564942 hasAuthorship W2047564942A5040403502 @default.
• W2047564942 hasAuthorship W2047564942A5065499336 @default.
• W2047564942 hasConcept C103319777 @default.
• W2047564942 hasConcept C115624301 @default.
• W2047564942 hasConcept C161790260 @default.
• W2047564942 hasConcept C178790620 @default.
• W2047564942 hasConcept C185592680 @default.
• W2047564942 hasConcept C2778460671 @default.
• W2047564942 hasConcept C2779336533 @default.
• W2047564942 hasConcept C32909587 @default.
• W2047564942 hasConcept C515207424 @default.
• W2047564942 hasConcept C55493867 @default.
• W2047564942 hasConcept C67524406 @default.
• W2047564942 hasConcept C71240020 @default.
• W2047564942 hasConcept C8010536 @default.
• W2047564942 hasConceptScore W2047564942C103319777 @default.
• W2047564942 hasConceptScore W2047564942C115624301 @default.
• W2047564942 hasConceptScore W2047564942C161790260 @default.
• W2047564942 hasConceptScore W2047564942C178790620 @default.
• W2047564942 hasConceptScore W2047564942C185592680 @default.
• W2047564942 hasConceptScore W2047564942C2778460671 @default.
• W2047564942 hasConceptScore W2047564942C2779336533 @default.
• W2047564942 hasConceptScore W2047564942C32909587 @default.
• W2047564942 hasConceptScore W2047564942C515207424 @default.
• W2047564942 hasConceptScore W2047564942C55493867 @default.
• W2047564942 hasConceptScore W2047564942C67524406 @default.
• W2047564942 hasConceptScore W2047564942C71240020 @default.
• W2047564942 hasConceptScore W2047564942C8010536 @default.
• W2047564942 hasIssue "16" @default.
• W2047564942 hasLocation W20475649421 @default.
• W2047564942 hasOpenAccess W2047564942 @default.
• W2047564942 hasPrimaryLocation W20475649421 @default.
• W2047564942 hasRelatedWork W15120608 @default.
• W2047564942 hasRelatedWork W2012345717 @default.
• W2047564942 hasRelatedWork W2012675768 @default.
• W2047564942 hasRelatedWork W2039374736 @default.
• W2047564942 hasRelatedWork W2075817299 @default.
• W2047564942 hasRelatedWork W2091436431 @default.
• W2047564942 hasRelatedWork W2463657710 @default.

• next