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- W2047577572 abstract "The influence on the N2O photocurrent of homogeneous competition for OH radicals between two organic solutes which form (as the result of hydrogen abstraction) radicals, one of which is reduced by the electrode, the other being oxidised, is considered theoretically. Such competition can be employed to investigate the kinetics of hydrogen abstraction in a case in which uncompetitive homogeneous destruction of OH radicals by a solute has no effect on the photocurrent. The influence of incomplete oxidation of alcohol radicals when a light pulse of short duration is employed is discussed, together with complications caused by adsorption of the organic solute. Competition for OH radicals between phenol and methanol points to a rate constant for H abstraction from phenol of ca. 2.8 × 109 l mol−1 s−1 and to rapid heterogeneous reduction of most of the C6H4OH radicals throughout the accessible potential range." @default.
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- W2047577572 date "1975-06-01" @default.
- W2047577572 modified "2023-09-23" @default.
- W2047577572 title "Use of homogeneous competition for OH radicals in electrochemical studies of H abstraction from organic molecules" @default.
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- W2047577572 doi "https://doi.org/10.1016/0022-0728(75)80042-8" @default.
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