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• W2047656912 abstract "Bicyclic Lactam 2 was transformed into α-cyanoenamine 8 in a four-step, high-yielding process. γ-Metalation of 8 was achieved using LiTMP in THF/HMPA, and the resultant homoenolate equivalent underwent stereoselective alkylation and subsequent hydrolysis to provide lactams of type 10 as a single diastereomer. Partial reduction and hydrolysis of lactams 10 furnished enantiopure 5-substituted cyclohexenones 13 in good overall yield." @default.
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• W2047656912 date "1997-06-01" @default.
• W2047656912 modified "2023-10-16" @default.
• W2047656912 title "Chiral bicyclic Lactams as homoenolate equivalents: An asymmetric route to 5-substituted cyclohexenones" @default.
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• W2047656912 doi "https://doi.org/10.1016/s0040-4020(97)90391-4" @default.
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