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• W2047668864 abstract "The effect of added solutes on the decay kinetics of primary positive ions in irradiated cyclohexane has been studied using the microwave absorption method. Absolute rate constants, in the range of 1 to 3.5 × 1011 M−1s−1, have been determined for the reaction of positive ioins with ethanol, ammonia, cyclopropane, benzene, dimethylaniline and biphenyl. For all of the above solutes the activation energy for reaction is found to be less than 1 kcal/mole. The rate constants obtained are compared with reactivity parameters available from steady-state radiolysis experiments. Taking for the yield of geminate ions a value of 5.0 (100eV)−1, the characteristic geminate ion lifetime, λ−1, in pure cyclohexane is estimated to be 2.2 ± 0.5 ps." @default.
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• W2047668864 date "1976-10-01" @default.
• W2047668864 modified "2023-09-25" @default.
• W2047668864 title "Rate constants for the reaction of positive ions with solutes in irradiated liquid cyclohexane" @default.
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• W2047668864 doi "https://doi.org/10.1016/0009-2614(76)85312-2" @default.
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