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• W2047717967 abstract "Short-lived intermediates often play key roles in determining the course of chemical reactions. Recently the combination of sophisticated laser techniques and supersonic free jet expansions has offered new insight into the structure and reactivity of such intermediates. Because of their extremely reactive nature the intermediates are produced in situ in the expansion. The free jet expansion provides cooling of the intermediates to very low temperatures, so that even complex organic free radicals and molecular ions can be identified and characterized. Radical-radical reactions and ionic cluster formation likewise proceed in the expansion and can be monitored by laser spectroscopy." @default.
• W2047717967 created "2016-06-24" @default.
• W2047717967 creator A5061947031 @default.
• W2047717967 date "1984-02-10" @default.
• W2047717967 modified "2023-10-17" @default.
• W2047717967 title "Chemistry and Chemical Intermediates in Supersonic Free Jet Expansions" @default.
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• W2047717967 doi "https://doi.org/10.1126/science.223.4636.545" @default.
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