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• W2047721972 abstract "An easier and more expedient synthesis of 2,6-(BrCH2C6H4)2-4-I-C6H3 (2) is reported. This material allowed easy synthesis of the new pincer ligand precursor 2,6-(4-CH3C6H4SCH2C6H4)2-4-I-C6H3 (3) in 87% yield. Compound 3 reacts with Pd2(dba)3 to give the new palladium pincer complex 4. Compound 4 has been fully characterized, including structural characterization by single crystal X-ray diffraction methods. The results of the crystallographic work on 4 reveal a twisted type pincer complex not unlike related terphenyl pincer complexes." @default.
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• W2047721972 date "2009-12-01" @default.
• W2047721972 modified "2023-10-16" @default.
• W2047721972 title "Improved synthesis of pincer ligand precursor, and synthesis and structural characterization of terphenyl scaffolded S–C–S palladium pincer complex" @default.
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• W2047721972 doi "https://doi.org/10.1016/j.inoche.2009.08.036" @default.
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