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• W2047732094 abstract "An investigation of durability characteristics of a pasted filamentary Ni catalyst was performed and extensive approaches for elucidating the degradation mechanism of the catalyst were undertaken. The H2 generation rate of pasted filamentary Ni catalyst gradually decreases with cycling and 76% of the initial H2 generation rate remains at 200 cycles. After 200 cycles, SEM images show an agglomeration of catalyst particles and a film on the pasted catalyst. An agglomeration of catalyst results in a reduction of specific surface area, as indicated by BET analysis, and a film on the pasted catalyst was formed by an accumulation of potassium originating from alkaline solution, and sodium and boron, which consists of Na2B4O7·10H2O, a potassium borate compound (KBxOy) and boron oxide (B2O3), as indicated by XRD and XPS analyses. Consequently, a deterioration of the catalyst upon hydrolysis of sodium borohydride results from agglomeration of the catalyst and the film formed on the catalyst." @default.
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• W2047732094 date "2004-10-01" @default.
• W2047732094 modified "2023-09-27" @default.
• W2047732094 title "Study on degradation of filamentary Ni catalyst on hydrolysis of sodium borohydride" @default.
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• W2047732094 doi "https://doi.org/10.1016/j.jallcom.2004.02.009" @default.
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