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- W2047737545 abstract "Abstract The evaporation of submicrometer ammonium nitrate (NH 4 NO 3 ) aerosol coated with an organic film was measured in order to determine the effect of the film on mass transfer rate and equilibration time of the semi-volatile inorganic. Ammonium nitrate (NH 4 NO 3 ) particles 100–200 nm in diameter were coated with dioctyl phthalate (DOP) and allowed to evaporate in a constant temperature laminar flow reactor. Evaporation rates for the organic-coated particles were compared to pure ammonium nitrate evaporation at 22 and 27°C. A decrease, up to 50%, in NH 4 NO 3 evaporation rate due to the presence of the DOP film was observed. The decrease in evaporation due to the DOP can be described mathematically at 22°C by a decrease in the accommodation coefficient for NH 4 NO 3 , α NH 4 NO 3 , from 0.4 (the pure NH 4 NO 3 value) to 0.25 for the DOP-coated NH 4 NO 3. Similarly, at 27°C, a decrease in α NH 4 NO 3 from 0.3 for the pure NH 4 NO 3 to 0.25 for the DOP-coated particles was estimated. The decrease in evaporation rates can also be explained by a decrease in NH 4 NO 3 effective diffusivity. The implications to NH 4 NO 3 formation and evaporation in the atmosphere are discussed." @default.
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- W2047737545 title "The effect of dioctyl phthalate films on the ammonium nitrate aerosol evaporation rate" @default.
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- W2047737545 doi "https://doi.org/10.1016/s1352-2310(00)00173-4" @default.
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