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- W2047773071 abstract "4-Alkyl-2,2,6,6-tetramethyl-1,4,2,6-oxaazadisilinanes RN[CH2Si(Me)2]2O [R = Me (1), i-Pr (2)] were synthesized by two methods which provided good yields up to 84%. Low temperature NMR study of compounds (1) and (2) revealed a frozen ring inversion with the energy barriers of 8.5 and 7.7 kcal/mol at 163 and 143 K, respectively, which is substantially lower than that for their carbon analog, N-methylmorpholine. DFT calculations performed on the example of molecule (1) showed that NMeax conformer to exist in the sofa conformation with the coplanar fragment CSiOSiC, and its NMeeq conformer in a flattened chair conformation. Copyright © 2009 John Wiley & Sons, Ltd." @default.
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- W2047773071 date "2009-09-30" @default.
- W2047773071 modified "2023-09-24" @default.
- W2047773071 title "4-Alkyl-2,2,6,6-tetramethyl-1,4,2,6-oxaazadisilinanes: synthesis, structure, and conformational analysis" @default.
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- W2047773071 doi "https://doi.org/10.1002/poc.1605" @default.
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