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- W2047791533 abstract "Reactions of trans-1-chloro-2-butene and of 3-chloro-1-butene with nickelocene give mixtures of (1-methyl-2-propenyl)-, (trans-2-butenyl)-, and (cis-2-butenyl)-cyclopentadienes. The reaction between π-crotyl-π-cyclopentadienylnickel and 5-chlorocyclopentadiene yields identical products. In the presence of tetrahcloromethane, 5-(trichloromethyl)cyclopentadiene is formed. Mechanisms involving oxidative addition and π-allylic nickel complexes are discussed." @default.
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- W2047791533 date "1976-03-01" @default.
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- W2047791533 title "Evidence for π-allylic nickel complexes as intermediates in the reactions of nickelocene with allylic chlorides" @default.
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- W2047791533 doi "https://doi.org/10.1016/s0022-328x(00)94453-x" @default.
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