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- W2047804545 abstract "The synthesis of the first chiral polyhydroxy diphosphine-Rh(I) catalyst for asymmetric hydrogenation is described. Based on a simple synthetic pathway starting from d-mannitol the new metal complex is constructed. A special feature of the approach is the protection of the air-sensitive phosphine groups by the catalytically active metal in the final synthetic steps. Therefore, tedious P-protection-deprotection procedures could be advantageously avoided. The new water-soluble catalyst hydrogenates functionalized olefins by up to 99.6% ee in water as solvent." @default.
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- W2047804545 date "1999-09-01" @default.
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- W2047804545 title "Synthesis of the first water-soluble chiral tetrahydroxy diphosphine Rh(I) catalyst for enantioselective hydrogenation" @default.
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