Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047835783> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2047835783 endingPage "260" @default.
- W2047835783 startingPage "242" @default.
- W2047835783 abstract "Abstract The adsorption of SO 2 on Ag(110) and the reaction of SO 2 with oxygen adatoms have been studied under ultrahigh vacuum conditions using low energy electron diffraction, temperature programmed reaction spectroscopy and photoelectron spectroscopy. Below 300 K, SO 2 adsorbs molecularly giving p(1×2) and c(4×2) LEED patterns at coverages of one half and three quarter monolayers. respectively. At intermediate coverages, streaked diffraction patterns, similar to those reported for noble gas and alkali metal adsorption on the (110) face of face-centered cubic metals were observed, indicating adsorption out of registry with the surface. A feature at low binding energy in the ultraviolet photoemission spectrum appeared which was assigned to a weak chemisorption bond to the surface via the sulfur, analogous to bonding observed in SO 2 -amine charge transfer complexes and in transition metal complexes. SO 2 exhibited three binding states on Ag(110) with binding energies of 41, 53 and 64 kJ mol −1 ; no decomposition on clean Ag(110) was observed. On oxygen pretreated Ag(110), SO 2 reacted with oxygen adatoms to form SO 3(a) , as determined by X-ray photoelectron spectroscopy. Reacting preadsorbed atomic oxygen in a p(2 × 1) structure with SO 2 resulted in a c(6 × 2) pattern for SO 3(a) . The adsorbed SO 3(a) decomposed and disproportionated upon heating to 500 K to yield SO 2( g ) , SO 4(a) and subsurface oxygen." @default.
- W2047835783 created "2016-06-24" @default.
- W2047835783 creator A5042069920 @default.
- W2047835783 creator A5088858135 @default.
- W2047835783 date "1984-02-01" @default.
- W2047835783 modified "2023-09-23" @default.
- W2047835783 title "Sulfur dioxide adsorption and reaction with atomic oxygen on the Ag(110) surface" @default.
- W2047835783 cites W1969012079 @default.
- W2047835783 cites W1981249299 @default.
- W2047835783 cites W1988818992 @default.
- W2047835783 cites W1990836280 @default.
- W2047835783 cites W1991689248 @default.
- W2047835783 cites W1992214743 @default.
- W2047835783 cites W2012322397 @default.
- W2047835783 cites W2013337128 @default.
- W2047835783 cites W2013791141 @default.
- W2047835783 cites W2016002426 @default.
- W2047835783 cites W2018605728 @default.
- W2047835783 cites W2019183935 @default.
- W2047835783 cites W2021066408 @default.
- W2047835783 cites W2021935730 @default.
- W2047835783 cites W2031750894 @default.
- W2047835783 cites W2032118718 @default.
- W2047835783 cites W2034968670 @default.
- W2047835783 cites W2037962799 @default.
- W2047835783 cites W2039140211 @default.
- W2047835783 cites W2044775293 @default.
- W2047835783 cites W2051459648 @default.
- W2047835783 cites W2059571315 @default.
- W2047835783 cites W2066657180 @default.
- W2047835783 cites W2070239635 @default.
- W2047835783 cites W2079397983 @default.
- W2047835783 cites W2080368307 @default.
- W2047835783 cites W2086543106 @default.
- W2047835783 cites W2087966123 @default.
- W2047835783 cites W2090172423 @default.
- W2047835783 cites W2091449128 @default.
- W2047835783 cites W2099586687 @default.
- W2047835783 cites W2135218265 @default.
- W2047835783 cites W2155495731 @default.
- W2047835783 cites W2243318360 @default.
- W2047835783 doi "https://doi.org/10.1016/0039-6028(84)90687-3" @default.
- W2047835783 hasPublicationYear "1984" @default.
- W2047835783 type Work @default.
- W2047835783 sameAs 2047835783 @default.
- W2047835783 citedByCount "85" @default.
- W2047835783 countsByYear W20478357832014 @default.
- W2047835783 countsByYear W20478357832015 @default.
- W2047835783 countsByYear W20478357832022 @default.
- W2047835783 countsByYear W20478357832023 @default.
- W2047835783 crossrefType "journal-article" @default.
- W2047835783 hasAuthorship W2047835783A5042069920 @default.
- W2047835783 hasAuthorship W2047835783A5088858135 @default.
- W2047835783 hasConcept C147789679 @default.
- W2047835783 hasConcept C150394285 @default.
- W2047835783 hasConcept C178790620 @default.
- W2047835783 hasConcept C179104552 @default.
- W2047835783 hasConcept C185592680 @default.
- W2047835783 hasConcept C2780447027 @default.
- W2047835783 hasConcept C2983054736 @default.
- W2047835783 hasConcept C518881349 @default.
- W2047835783 hasConcept C540031477 @default.
- W2047835783 hasConceptScore W2047835783C147789679 @default.
- W2047835783 hasConceptScore W2047835783C150394285 @default.
- W2047835783 hasConceptScore W2047835783C178790620 @default.
- W2047835783 hasConceptScore W2047835783C179104552 @default.
- W2047835783 hasConceptScore W2047835783C185592680 @default.
- W2047835783 hasConceptScore W2047835783C2780447027 @default.
- W2047835783 hasConceptScore W2047835783C2983054736 @default.
- W2047835783 hasConceptScore W2047835783C518881349 @default.
- W2047835783 hasConceptScore W2047835783C540031477 @default.
- W2047835783 hasIssue "1" @default.
- W2047835783 hasLocation W20478357831 @default.
- W2047835783 hasOpenAccess W2047835783 @default.
- W2047835783 hasPrimaryLocation W20478357831 @default.
- W2047835783 hasRelatedWork W1597429558 @default.
- W2047835783 hasRelatedWork W1983109807 @default.
- W2047835783 hasRelatedWork W2024118286 @default.
- W2047835783 hasRelatedWork W2026435069 @default.
- W2047835783 hasRelatedWork W2035537016 @default.
- W2047835783 hasRelatedWork W2049947086 @default.
- W2047835783 hasRelatedWork W2076393266 @default.
- W2047835783 hasRelatedWork W2319557984 @default.
- W2047835783 hasRelatedWork W2949170555 @default.
- W2047835783 hasRelatedWork W2949517020 @default.
- W2047835783 hasVolume "137" @default.
- W2047835783 isParatext "false" @default.
- W2047835783 isRetracted "false" @default.
- W2047835783 magId "2047835783" @default.
- W2047835783 workType "article" @default.