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• W2047842686 abstract "The vibrational state distribution of NO formed in the radical–radical reaction N+OH→NO(v′≤9)+H; ΔH00=−204.0 kJ mol−1 has been determined using a pulse-and-probe technique. OH radicals were generated by pulsed laser photolysis of H2O2 at 266 nm in a flow of N2 which had been passed through a microwave discharge to produce N atoms. The vibrational distribution of NO, measured by laser-induced fluorescence (LIF) spectroscopy, is similar to that predicted by phase-space theory and corresponds to an average yield of ca. 31% of the energy available to the reaction products. Experiments in which LIF signals were observed as the pulse–probe time delay was varied showed that populations within different vibrational levels (v=0–8) displayed similar kinetics, consistent with rapid removal of NO(v) by reaction with N atoms, N+NO(v)→N2+O, at rates which exhibit a mild dependence on v." @default.
• W2047842686 created "2016-06-24" @default.
• W2047842686 creator A5027449777 @default.
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• W2047842686 date "1993-04-15" @default.
• W2047842686 modified "2023-09-24" @default.
• W2047842686 title "Vibrational state specificity and selectivity in the reactions N+OH→NO(<i>v</i>)+H and N+NO(<i>v</i>)→N2+O" @default.
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• W2047842686 doi "https://doi.org/10.1063/1.464821" @default.
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