Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047887833> ?p ?o ?g. }
- W2047887833 endingPage "793" @default.
- W2047887833 startingPage "789" @default.
- W2047887833 abstract "In an effort to assist in the preparation of metal-containing ligands for the androgen receptor, we have synthesized the first oxorhenium(V) complexes containing a pendant testosterone moiety. The key step in the synthesis involves the copper-catalysed, α-selective 1,6-Michael addition of a 4-pentenylmagnesium bromide to 6-dehydrotestosterone 17β-acetate. The α-stereoselectivity is governed by the presence of the C-19 methyl group. The absolute configurations of the epimers were investigated by 1H-NMR studies. Further chemical transformations of the 7α-pentenyl spacer introduced the terminal thiol group, needed for complex formation. The complex formation was accomplished by the “3+1” mixed-ligand concept using two different rhenium precursors. The obtained complexes differ with respect to the central donor atom of the tridentate ligand part, namely, S and O." @default.
- W2047887833 created "2016-06-24" @default.
- W2047887833 creator A5013037939 @default.
- W2047887833 creator A5014005682 @default.
- W2047887833 creator A5027838864 @default.
- W2047887833 creator A5047340171 @default.
- W2047887833 date "1998-06-01" @default.
- W2047887833 modified "2023-09-26" @default.
- W2047887833 title "Synthesis of Oxorhenium(V) Complexes Derived from 7α-Functionalized Testosterone: First Rhenium-Containing Testosterone Derivatives" @default.
- W2047887833 cites W1646536031 @default.
- W2047887833 cites W1967424254 @default.
- W2047887833 cites W1970120424 @default.
- W2047887833 cites W1972874555 @default.
- W2047887833 cites W1981244712 @default.
- W2047887833 cites W2021191018 @default.
- W2047887833 cites W2023882993 @default.
- W2047887833 cites W2032811767 @default.
- W2047887833 cites W2039864977 @default.
- W2047887833 cites W2051743481 @default.
- W2047887833 cites W2069607377 @default.
- W2047887833 cites W2080228734 @default.
- W2047887833 cites W2086312603 @default.
- W2047887833 cites W2950185726 @default.
- W2047887833 cites W2950442424 @default.
- W2047887833 cites W4235747212 @default.
- W2047887833 cites W7946580 @default.
- W2047887833 cites W86879710 @default.
- W2047887833 doi "https://doi.org/10.1002/(sici)1099-0682(199806)1998:6<789::aid-ejic789>3.0.co;2-z" @default.
- W2047887833 hasPublicationYear "1998" @default.
- W2047887833 type Work @default.
- W2047887833 sameAs 2047887833 @default.
- W2047887833 citedByCount "21" @default.
- W2047887833 countsByYear W20478878332012 @default.
- W2047887833 countsByYear W20478878332013 @default.
- W2047887833 countsByYear W20478878332018 @default.
- W2047887833 countsByYear W20478878332020 @default.
- W2047887833 countsByYear W20478878332021 @default.
- W2047887833 crossrefType "journal-article" @default.
- W2047887833 hasAuthorship W2047887833A5013037939 @default.
- W2047887833 hasAuthorship W2047887833A5014005682 @default.
- W2047887833 hasAuthorship W2047887833A5027838864 @default.
- W2047887833 hasAuthorship W2047887833A5047340171 @default.
- W2047887833 hasConcept C116569031 @default.
- W2047887833 hasConcept C121608353 @default.
- W2047887833 hasConcept C126322002 @default.
- W2047887833 hasConcept C155647269 @default.
- W2047887833 hasConcept C161790260 @default.
- W2047887833 hasConcept C170493617 @default.
- W2047887833 hasConcept C178790620 @default.
- W2047887833 hasConcept C181647583 @default.
- W2047887833 hasConcept C185592680 @default.
- W2047887833 hasConcept C203130289 @default.
- W2047887833 hasConcept C2776300020 @default.
- W2047887833 hasConcept C2776568683 @default.
- W2047887833 hasConcept C2780192828 @default.
- W2047887833 hasConcept C505216180 @default.
- W2047887833 hasConcept C544153396 @default.
- W2047887833 hasConcept C55493867 @default.
- W2047887833 hasConcept C61367390 @default.
- W2047887833 hasConcept C71240020 @default.
- W2047887833 hasConcept C71924100 @default.
- W2047887833 hasConceptScore W2047887833C116569031 @default.
- W2047887833 hasConceptScore W2047887833C121608353 @default.
- W2047887833 hasConceptScore W2047887833C126322002 @default.
- W2047887833 hasConceptScore W2047887833C155647269 @default.
- W2047887833 hasConceptScore W2047887833C161790260 @default.
- W2047887833 hasConceptScore W2047887833C170493617 @default.
- W2047887833 hasConceptScore W2047887833C178790620 @default.
- W2047887833 hasConceptScore W2047887833C181647583 @default.
- W2047887833 hasConceptScore W2047887833C185592680 @default.
- W2047887833 hasConceptScore W2047887833C203130289 @default.
- W2047887833 hasConceptScore W2047887833C2776300020 @default.
- W2047887833 hasConceptScore W2047887833C2776568683 @default.
- W2047887833 hasConceptScore W2047887833C2780192828 @default.
- W2047887833 hasConceptScore W2047887833C505216180 @default.
- W2047887833 hasConceptScore W2047887833C544153396 @default.
- W2047887833 hasConceptScore W2047887833C55493867 @default.
- W2047887833 hasConceptScore W2047887833C61367390 @default.
- W2047887833 hasConceptScore W2047887833C71240020 @default.
- W2047887833 hasConceptScore W2047887833C71924100 @default.
- W2047887833 hasIssue "6" @default.
- W2047887833 hasLocation W20478878331 @default.
- W2047887833 hasOpenAccess W2047887833 @default.
- W2047887833 hasPrimaryLocation W20478878331 @default.
- W2047887833 hasRelatedWork W1976389640 @default.
- W2047887833 hasRelatedWork W1979213907 @default.
- W2047887833 hasRelatedWork W1990113808 @default.
- W2047887833 hasRelatedWork W1995317016 @default.
- W2047887833 hasRelatedWork W2117444515 @default.
- W2047887833 hasRelatedWork W2162820747 @default.
- W2047887833 hasRelatedWork W2504670837 @default.
- W2047887833 hasRelatedWork W2949471472 @default.
- W2047887833 hasRelatedWork W2951155388 @default.
- W2047887833 hasRelatedWork W2952508841 @default.
- W2047887833 hasVolume "1998" @default.
- W2047887833 isParatext "false" @default.
- W2047887833 isRetracted "false" @default.
- W2047887833 magId "2047887833" @default.