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- W2047896114 abstract "Solutions containing hydrochloric acid in concentrations less than 1·0 molar and molybdate ions in concentrations less than 10−4 molar give polarograms containing one or three waves. The single wave observed in 0·5–0·7 M hydrochloric acid and the middle wave of the three observed in more dilute acid have reversible two electron characteristics. The half-wave potential of this wave is given by the equation: E12 = − 0·080 0·12 log (H+) + 0·035 log (Cl−) corresponding to the electrochemical equation: Mo(VI) + 4H+ + Cl− + 2e → Mo(IV) Evidence that the chemically unstable Mo(IV) is the primary reduction product is discussed." @default.
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- W2047896114 date "1962-11-01" @default.
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- W2047896114 title "Polarography of hexavalent molybdenum in hydrochloric acid" @default.
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- W2047896114 doi "https://doi.org/10.1016/0022-1902(62)80085-2" @default.
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