Matches in SemOpenAlex for { <https://semopenalex.org/work/W2047923508> ?p ?o ?g. }
- W2047923508 endingPage "16020" @default.
- W2047923508 startingPage "16012" @default.
- W2047923508 abstract "The liquid−liquid interface between semifluorinated alkane diblock copolymers of the form F3C(CF2)n−1(CH2)m−1CH3 and water, protonated alkanes, and perfluorinated alkanes are studied by fully atomistic molecular dynamics simulations. A modified version of the OPLS-AA (Optimized Parameter for Liquid Simulation All-Atom) force field of Jorgensen et al. has been used to study the interfacial behavior of semifluorinated diblocks. Aqueous interfaces are found to be sharp, with correspondingly large values of the interfacial tension. Due to the reduced hydrophobicity of the protonated block compared to the fluorinated block, hydrogen enhancement is observed at the interface. Water dipoles in the interfacial region are found to be oriented nearly parallel to the liquid−liquid interface. A number of protonated alkanes and perfluorinated alkanes are found to be mutually miscible with the semifluorinated diblocks. For these liquids, interdiffusion follows the expected Fickian behavior, and concentration-dependent diffusivities are determined." @default.
- W2047923508 created "2016-06-24" @default.
- W2047923508 creator A5001454717 @default.
- W2047923508 creator A5049127548 @default.
- W2047923508 creator A5067183345 @default.
- W2047923508 creator A5072768235 @default.
- W2047923508 date "2008-10-25" @default.
- W2047923508 modified "2023-09-23" @default.
- W2047923508 title "Liquid−Liquid Interfaces of Semifluorinated Alkane Diblock Copolymers with Water, Alkanes, and Perfluorinated Alkanes" @default.
- W2047923508 cites W1968196838 @default.
- W2047923508 cites W1968481066 @default.
- W2047923508 cites W1972583800 @default.
- W2047923508 cites W1974128000 @default.
- W2047923508 cites W1974724221 @default.
- W2047923508 cites W1974731134 @default.
- W2047923508 cites W1975236560 @default.
- W2047923508 cites W1978791569 @default.
- W2047923508 cites W1979691568 @default.
- W2047923508 cites W1980079863 @default.
- W2047923508 cites W1980929991 @default.
- W2047923508 cites W1982352044 @default.
- W2047923508 cites W1982821296 @default.
- W2047923508 cites W1983805127 @default.
- W2047923508 cites W1984570344 @default.
- W2047923508 cites W1985046482 @default.
- W2047923508 cites W1987218170 @default.
- W2047923508 cites W1987395781 @default.
- W2047923508 cites W1989252093 @default.
- W2047923508 cites W1992882086 @default.
- W2047923508 cites W1996928524 @default.
- W2047923508 cites W1997981805 @default.
- W2047923508 cites W1999277179 @default.
- W2047923508 cites W2002004665 @default.
- W2047923508 cites W2004291098 @default.
- W2047923508 cites W2004768754 @default.
- W2047923508 cites W2007602014 @default.
- W2047923508 cites W2008418858 @default.
- W2047923508 cites W2009550115 @default.
- W2047923508 cites W2009714475 @default.
- W2047923508 cites W2011974591 @default.
- W2047923508 cites W2012811285 @default.
- W2047923508 cites W2018629314 @default.
- W2047923508 cites W2018706165 @default.
- W2047923508 cites W2020764903 @default.
- W2047923508 cites W2020968829 @default.
- W2047923508 cites W2023988070 @default.
- W2047923508 cites W2026404635 @default.
- W2047923508 cites W2028560816 @default.
- W2047923508 cites W2029305313 @default.
- W2047923508 cites W2029493564 @default.
- W2047923508 cites W2030697575 @default.
- W2047923508 cites W2031105162 @default.
- W2047923508 cites W2031107710 @default.
- W2047923508 cites W2033675919 @default.
- W2047923508 cites W2035106001 @default.
- W2047923508 cites W2035674677 @default.
- W2047923508 cites W2036150237 @default.
- W2047923508 cites W2038875525 @default.
- W2047923508 cites W2042467552 @default.
- W2047923508 cites W2047514627 @default.
- W2047923508 cites W2049475242 @default.
- W2047923508 cites W2051381895 @default.
- W2047923508 cites W2054195857 @default.
- W2047923508 cites W2059334877 @default.
- W2047923508 cites W2063226885 @default.
- W2047923508 cites W2069181636 @default.
- W2047923508 cites W2072345208 @default.
- W2047923508 cites W2083735669 @default.
- W2047923508 cites W2084969417 @default.
- W2047923508 cites W2084992405 @default.
- W2047923508 cites W2085478435 @default.
- W2047923508 cites W2087174959 @default.
- W2047923508 cites W2087849941 @default.
- W2047923508 cites W2088584980 @default.
- W2047923508 cites W2090555333 @default.
- W2047923508 cites W2092610262 @default.
- W2047923508 cites W2095464219 @default.
- W2047923508 cites W2097130834 @default.
- W2047923508 cites W2100348914 @default.
- W2047923508 cites W2100511296 @default.
- W2047923508 cites W2110128220 @default.
- W2047923508 cites W2111449194 @default.
- W2047923508 cites W2112228380 @default.
- W2047923508 cites W2117456169 @default.
- W2047923508 cites W2119132089 @default.
- W2047923508 cites W2126119374 @default.
- W2047923508 cites W2136971960 @default.
- W2047923508 cites W2153546486 @default.
- W2047923508 cites W2155194356 @default.
- W2047923508 cites W2160431999 @default.
- W2047923508 cites W2170560995 @default.
- W2047923508 cites W2770469415 @default.
- W2047923508 cites W3099284343 @default.
- W2047923508 cites W4229858891 @default.
- W2047923508 cites W4361865001 @default.
- W2047923508 doi "https://doi.org/10.1021/jp805574f" @default.
- W2047923508 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19367794" @default.
- W2047923508 hasPublicationYear "2008" @default.