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- W2047958051 abstract "It is confirmed that the loss of HO˙ from the molecular ion of o-nitrotoluene involves exclusively a hydrogen from the methyl group. However, in higher homologues hydrogen atoms from non-benzylic sites are also implicated. With such compounds this fragmentation mode is shown not only by the ortho but, to a lesser extent, by the meta and para isomers as well. The proportion of the total ion current borne by the [M – 17]+ ion follows the order ortho > meta > para, which is attributed to substituent migration around the ring with a hydroxyl radical only being lost when the groups are on adjacent ring atoms. Other ions present in the spectra point to interaction between substituents to form a new heterocyclic ring." @default.
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- W2047958051 date "1979-08-01" @default.
- W2047958051 modified "2023-09-27" @default.
- W2047958051 title "The Loss of a hydroxyl group from the molecular ions of alkylnitrobenzenes" @default.
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- W2047958051 doi "https://doi.org/10.1002/oms.1210140811" @default.
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