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• W2047985218 abstract "LiMn2−XCuXO4 (X 0.4) lowered the symmetry from Fd3m to P4332. The Cu2+-substitution led to the enhancement of low-temperature magnetic susceptibility M/H. Simultaneously, the Weiss constant changed its sign from negative to positive. This implied that the dominant exchange interaction varies from antiferromagnetic to ferromagnetic couplings. For the compounds with X = 0.5, the magnetic moment per chemical formula at 4.2 K was 3.99μB and Curie temperature was approximately 39 K. The value of the magnetic moment was close to the theoretical value, in which a ferrimagnetic collinear spin structure was attained: the spins of the Cu2+ ion were antiferromagnetically coupled with those of the Mn4+ ion. Additionally, the magnetic properties of Li–Mn–Cu spinel oxides were briefly discussed, comparing them with those of Li–Mn–M (M = Ni, Mg) spinel oxides." @default.
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• W2047985218 date "2009-06-04" @default.
• W2047985218 modified "2023-09-25" @default.
• W2047985218 title "Synthesis and magnetic properties of Li–Mn–Cu spinel oxides" @default.
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• W2047985218 doi "https://doi.org/10.1088/0022-3727/42/12/125007" @default.
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