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- W2047993443 abstract "New compounds of elements of group 15 with silicon have been prepared. By using the bulky hypersilyl substituent -Si(SiMe3)3 unusual structures could be stabilised in such a way that even the refluxing in an ether/H2O mixture for several days resulted in only minor P-Si bond cleavage. The choice of suitable conditions led to unexpected rearrangements yielding cyclic and cage-like structures, like hexakis(trimethylsily1)cyclotrisilane. These structures have been characterised by X-ray diffraction and 31P- and 29Si-NMR spectroscopy. The 31P-NMR spectrum of P7[(SiMe3)3Si]3 shows the complex splitting pattern of an A[MX]3 system." @default.
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- W2047993443 date "2000-01-17" @default.
- W2047993443 modified "2023-09-23" @default.
- W2047993443 title "Hypersilyl Compounds of Elements of Group 15" @default.
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- W2047993443 doi "https://doi.org/10.1002/9783527619917.ch61" @default.
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