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• W2047995723 abstract "We synthesized CuSbS2 (CAS), CuSbSe2 (CASe), and their solid solutions by only a mechanochemical process. CAS powder with good crystallinity was obtained by post-heating at 400 and 500 °C. CASe powder with good crystallinity was obtained by post-heating at 400 and 450 °C. The CuSb(S1 -xSex)2 (CASSe) solid solutions with 0.0 ≤ x ≤ 1.0 were synthesized by post-heating at 450 °C. The crystal structure of CASSe was analyzed by Rietveld refinement using X-ray diffraction data. CAS, CASe, and CASSe solid solutions have a chalcostibite structure with an orthorhombic system of space group (Pnma). Both indirect and direct band gap energies of CASSe solid solutions were estimated by the diffuse reflectance spectra of ultraviolet/visible/near-infrared (UV-vis-NIR) spectroscopy. The indirect band gap of the CASSe solid solution linearly decreased from 1.40 eV of CuSbS2 (x = 0.0) to 1.04 eV of CuSbSe2 (x = 1.0). The direct band gap of the CASSe solid solution linearly decreased from 1.45 eV of CuSbS2 (x = 0.0) to 1.08 eV of CuSbSe2 (x = 1.0). CuSbS0.8Se1.2 (x = 0.6) and CuSbS0.4Se1.6 (x = 0.8) had a suitable band gap of about 1.15 eV for an absorber material of a high-efficiency thin-film polycrystalline solar cell." @default.
• W2047995723 created "2016-06-24" @default.
• W2047995723 creator A5031743207 @default.
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• W2047995723 date "2015-05-01" @default.
• W2047995723 modified "2023-09-30" @default.
• W2047995723 title "Crystallographic and optical properties of CuSbS 2 and CuSb(S 1-x Se x ) 2 solid solution" @default.
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• W2047995723 doi "https://doi.org/10.1016/j.tsf.2014.11.029" @default.
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