FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048010957> ?p ?o ?g. }

• W2048010957 endingPage "831" @default.
• W2048010957 startingPage "826" @default.
• W2048010957 abstract "The interaction of meso-tri(4-sulfonatophenyl)mono(4-carboxyphenyl) porphyrin (C1TPP) with 2,4,6-trinitrotoluene (TNT) has been explored by UV-vis and fluorescence spectroscopy. The influence of temperature on the interaction has also been studied. C1TPP binds to TNT at pH 7.0 at room temperature via 1.94 kcal/mole hydrogen bonds with absorbance loss at 412-413 nm and the appearance of a new peak at 422-424 nm. The hydrogen binding of TNT to C1TPP was confirmed by the dissolution of the complex upon the addition of urea. Increasing the temperature results in the appearance of a new absorbance peak at 540 nm and absorbance loss at 515 nm with activation energy of 29.7 kcal/mole in the range of the hydrophobic bond energy. This suggests the hydrophobic bonding of TNT with the pyrrole nitrogens in the porphyrin. Increasing the concentration of the TNT in the solution quenches the fluorescence of the porphyrin following the Stern-Volmer equation. The association constants calculated from absorbance and fluorescence are expectedly similar." @default.
• W2048010957 created "2016-06-24" @default.
• W2048010957 creator A5036952362 @default.
• W2048010957 creator A5066251676 @default.
• W2048010957 date "2008-06-01" @default.
• W2048010957 modified "2023-09-26" @default.
• W2048010957 title "Early events in 2,4,6-trinitrotoluene (TNT) degradation by porphyrins: Binding of TNT to porphyrin by hydrophobic and hydrogen bonds" @default.
• W2048010957 cites W1735218083 @default.
• W2048010957 cites W1803680760 @default.
• W2048010957 cites W1965311023 @default.
• W2048010957 cites W1972144290 @default.
• W2048010957 cites W1974727376 @default.
• W2048010957 cites W1978939325 @default.
• W2048010957 cites W1984174178 @default.
• W2048010957 cites W1992030908 @default.
• W2048010957 cites W1997367115 @default.
• W2048010957 cites W2003912173 @default.
• W2048010957 cites W2026163679 @default.
• W2048010957 cites W2027831075 @default.
• W2048010957 cites W2030112473 @default.
• W2048010957 cites W2032695201 @default.
• W2048010957 cites W2034575910 @default.
• W2048010957 cites W2039607212 @default.
• W2048010957 cites W2040184556 @default.
• W2048010957 cites W2045777307 @default.
• W2048010957 cites W2050772108 @default.
• W2048010957 cites W2051330433 @default.
• W2048010957 cites W2052323162 @default.
• W2048010957 cites W2052614716 @default.
• W2048010957 cites W2055676171 @default.
• W2048010957 cites W2067615376 @default.
• W2048010957 cites W2077567454 @default.
• W2048010957 cites W2082117699 @default.
• W2048010957 cites W2090851715 @default.
• W2048010957 cites W2092186962 @default.
• W2048010957 cites W2107868459 @default.
• W2048010957 cites W2110333823 @default.
• W2048010957 cites W2161339332 @default.
• W2048010957 cites W2162144213 @default.
• W2048010957 cites W4248456721 @default.
• W2048010957 doi "https://doi.org/10.1016/j.jhazmat.2007.10.098" @default.
• W2048010957 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18063299" @default.
• W2048010957 hasPublicationYear "2008" @default.
• W2048010957 type Work @default.
• W2048010957 sameAs 2048010957 @default.
• W2048010957 citedByCount "14" @default.
• W2048010957 countsByYear W20480109572012 @default.
• W2048010957 countsByYear W20480109572013 @default.
• W2048010957 countsByYear W20480109572014 @default.
• W2048010957 countsByYear W20480109572015 @default.
• W2048010957 countsByYear W20480109572018 @default.
• W2048010957 countsByYear W20480109572020 @default.
• W2048010957 countsByYear W20480109572022 @default.
• W2048010957 crossrefType "journal-article" @default.
• W2048010957 hasAuthorship W2048010957A5036952362 @default.
• W2048010957 hasAuthorship W2048010957A5066251676 @default.
• W2048010957 hasConcept C112887158 @default.
• W2048010957 hasConcept C121332964 @default.
• W2048010957 hasConcept C147789679 @default.
• W2048010957 hasConcept C178790620 @default.
• W2048010957 hasConcept C185592680 @default.
• W2048010957 hasConcept C2779480358 @default.
• W2048010957 hasConcept C32909587 @default.
• W2048010957 hasConcept C43617362 @default.
• W2048010957 hasConcept C62520636 @default.
• W2048010957 hasConcept C75473681 @default.
• W2048010957 hasConcept C88380143 @default.
• W2048010957 hasConcept C91881484 @default.
• W2048010957 hasConcept C98015330 @default.
• W2048010957 hasConceptScore W2048010957C112887158 @default.
• W2048010957 hasConceptScore W2048010957C121332964 @default.
• W2048010957 hasConceptScore W2048010957C147789679 @default.
• W2048010957 hasConceptScore W2048010957C178790620 @default.
• W2048010957 hasConceptScore W2048010957C185592680 @default.
• W2048010957 hasConceptScore W2048010957C2779480358 @default.
• W2048010957 hasConceptScore W2048010957C32909587 @default.
• W2048010957 hasConceptScore W2048010957C43617362 @default.
• W2048010957 hasConceptScore W2048010957C62520636 @default.
• W2048010957 hasConceptScore W2048010957C75473681 @default.
• W2048010957 hasConceptScore W2048010957C88380143 @default.
• W2048010957 hasConceptScore W2048010957C91881484 @default.
• W2048010957 hasConceptScore W2048010957C98015330 @default.
• W2048010957 hasIssue "1-3" @default.
• W2048010957 hasLocation W20480109571 @default.
• W2048010957 hasLocation W20480109572 @default.
• W2048010957 hasOpenAccess W2048010957 @default.
• W2048010957 hasPrimaryLocation W20480109571 @default.
• W2048010957 hasRelatedWork W1971350018 @default.
• W2048010957 hasRelatedWork W1979569657 @default.
• W2048010957 hasRelatedWork W1983379401 @default.
• W2048010957 hasRelatedWork W2005552449 @default.
• W2048010957 hasRelatedWork W2045211923 @default.
• W2048010957 hasRelatedWork W2052940040 @default.
• W2048010957 hasRelatedWork W2060216766 @default.
• W2048010957 hasRelatedWork W2160031308 @default.
• W2048010957 hasRelatedWork W2779371931 @default.
• W2048010957 hasRelatedWork W3036745168 @default.
• W2048010957 hasVolume "154" @default.

• next