Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048016054> ?p ?o ?g. }
- W2048016054 endingPage "3462" @default.
- W2048016054 startingPage "3457" @default.
- W2048016054 abstract "Reaction of the platinum iminoboryl complex trans-[(Cy3P)2(Br)Pt(B≡NSiMe3)] (Cy = cyclohexyl) toward covalent element−hydrogen bonds of inverse polarity led to regiospecific formation of the corresponding trans products of 1,2-dipolar addition. Hydrogen bromide reversibly adds to the B≡N triple bond, and despite the close proximity of the bromide to the trimethylsilyl substituent, the hydrobromination adduct trans-[(Cy3P)2BrPt{B(Br)N(H)SiMe3}] did not show any signs of bromosilane elimination. Furthermore, the reaction of trans-[(Cy3P)2(Br)Pt(B≡NSiMe3)] and trans-[(Cy3P)2Pt(B≡NSiMe3)(C≡CPh)] with the hydroboration reagent catecholatoborane was probed, revealing in both cases clean 1:1 reaction of the reagents. Whereas the reaction product of the latter complex is inherently unstable, both the mono- and the dinuclear hydroboration products of trans-[(Cy3P)2(Br)Pt(B≡NSiMe3)] could be isolated and fully characterized including X-ray diffraction analysis." @default.
- W2048016054 created "2016-06-24" @default.
- W2048016054 creator A5038029240 @default.
- W2048016054 creator A5046951517 @default.
- W2048016054 creator A5050323905 @default.
- W2048016054 creator A5056569207 @default.
- W2048016054 date "2010-07-12" @default.
- W2048016054 modified "2023-10-16" @default.
- W2048016054 title "Reactivity of Platinum Iminoboryl Complexes toward Covalent Element−Hydrogen Bonds of Opposing Polarity" @default.
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