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- W2048018506 abstract "We present transient resonance Raman spectra that demonstrate that the iso-iodoform photoproduct is mainly associated with the ∼400 nm transient absorption band observed following excitation of iodoform in the solution phase. Comparison of our present results with previously reported gas-phase experiments and results for the closely related diiodomethane molecular system suggests that solvation gives rise to noticeable formation of the iso-iodoform photoproduct by some recombination of the initially formed CHI2 and I photofragments within a solvent cage." @default.
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- W2048018506 date "2000-06-01" @default.
- W2048018506 modified "2023-10-14" @default.
- W2048018506 title "Solvation effects on the iodoform ultraviolet direct photodissociation reaction: opening the photoisomerization channel" @default.
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- W2048018506 doi "https://doi.org/10.1016/s0009-2614(00)00561-3" @default.
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