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• W2048021262 endingPage "462" @default.
• W2048021262 startingPage "458" @default.
• W2048021262 abstract "Absolute rate constants for the reaction of OH radicals with vinyl fluoride, vinyl chloride, and vinyl bromide have been determined over the temperature range 299–426 °K using a flash photolysis–resonance fluorescence technique. The Arrhenius expressions obtained were k (CH2=CHF) = 1.48×10−12e(775±300)/RT cm3 molecule−1 sec−1, k (CH2=CHCl) = 1.14×10−12e(1045±300)/RT cm3 molecule−1 sec−1, and k (CH2=CHBr) = 1.79×10−12e(805±300)/RT cm3 molecule−1 sec−1, with rate constants at room temperature of (5.56±0.56) ×10−12 cm3 molecule−1 sec−1, (6.60±0.66) ×10−12 cm3 molecule−1 sec−1, and (6.81±0.69) ×10−12 cm3 molecule−1 sec−1 for CH2=CHF, CH2=CHCl, and CH2=CHBr, respectively." @default.
• W2048021262 created "2016-06-24" @default.
• W2048021262 creator A5045247516 @default.
• W2048021262 creator A5067631967 @default.
• W2048021262 date "1977-07-15" @default.
• W2048021262 modified "2023-10-17" @default.
• W2048021262 title "Rate constants for the reaction of OH radicals with CH2=CHF, CH2=CHCl, and CH2=CHBr over the temperature range 299–426 °K" @default.
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• W2048021262 doi "https://doi.org/10.1063/1.434889" @default.
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