FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048040403> ?p ?o ?g. }

• W2048040403 endingPage "768" @default.
• W2048040403 startingPage "755" @default.
• W2048040403 abstract "The new compounds [M(NO)(PPh3)2(η2-C60)] (M = Co 1 or Rh 2), [RuX(NO)(PPh3)2(η2-C60)] (X = Cl 3 or H 4), [Re2H8(PMe3)4(η2: η2′-C60)] 5 and [TaH(η-C5H5)2(η2-C60)] have been prepared and characterised. Crystal structures have been determined for 3 and 5 and show typical η2 co-ordination of C60 in the former, but a rare example of η4 co-ordination in the latter. The soluble adducts 1, 2, 4, 5 and [M(CO)4(η2-C60)] (M = Ru 7 or Fe 8) have been electrochemically reversibly reduced up to the dianion and to the trianion for 4. The E° values are shifted to slightly less negative values than for C60 itself in consonance with the reduction in the number of fullerene double bonds. Addition of the electrophiles I2, maleic anhydride or PPh3 to 1 or 2 easily regenerated free C60. The presence of an isobenzofuran side chain in C60(C20H14O) prevents attack by the incoming metal centre Fe(CO)4 at adjacent double bonds and results in inequivalency of the remaining double bonds and a mixture of regioisomeric products. However, the isobenzofuran side chain may be displaced by Pd(PPh3)2 or [Co(η-C5H5)2] resulting in the formation of [Pd(PPh3)2(η2-C60)] or [Co(η-C5H5)2]+[C60]–." @default.
• W2048040403 created "2016-06-24" @default.
• W2048040403 creator A5008971106 @default.
• W2048040403 creator A5032719662 @default.
• W2048040403 creator A5040967190 @default.
• W2048040403 creator A5070334233 @default.
• W2048040403 date "1998-01-01" @default.
• W2048040403 modified "2023-09-23" @default.
• W2048040403 title "New transition-metal derivatives of the fullerene C60" @default.
• W2048040403 cites W1971754027 @default.
• W2048040403 cites W1973840378 @default.
• W2048040403 cites W1981791480 @default.
• W2048040403 cites W1981833282 @default.
• W2048040403 cites W1982678978 @default.
• W2048040403 cites W1983340497 @default.
• W2048040403 cites W1988841674 @default.
• W2048040403 cites W1992409282 @default.
• W2048040403 cites W2001565573 @default.
• W2048040403 cites W2007477411 @default.
• W2048040403 cites W2008705948 @default.
• W2048040403 cites W2013450848 @default.
• W2048040403 cites W2020015847 @default.
• W2048040403 cites W2023151126 @default.
• W2048040403 cites W2026095571 @default.
• W2048040403 cites W2028667489 @default.
• W2048040403 cites W2030795278 @default.
• W2048040403 cites W2059326094 @default.
• W2048040403 cites W2060176743 @default.
• W2048040403 cites W2098677114 @default.
• W2048040403 cites W2101748147 @default.
• W2048040403 cites W225395028 @default.
• W2048040403 cites W2274998050 @default.
• W2048040403 cites W233301416 @default.
• W2048040403 cites W242996491 @default.
• W2048040403 cites W2950252579 @default.
• W2048040403 cites W2952815708 @default.
• W2048040403 cites W3005349872 @default.
• W2048040403 doi "https://doi.org/10.1039/a707618e" @default.
• W2048040403 hasPublicationYear "1998" @default.
• W2048040403 type Work @default.
• W2048040403 sameAs 2048040403 @default.
• W2048040403 citedByCount "52" @default.
• W2048040403 countsByYear W20480404032012 @default.
• W2048040403 countsByYear W20480404032013 @default.
• W2048040403 countsByYear W20480404032016 @default.
• W2048040403 countsByYear W20480404032018 @default.
• W2048040403 countsByYear W20480404032022 @default.
• W2048040403 crossrefType "journal-article" @default.
• W2048040403 hasAuthorship W2048040403A5008971106 @default.
• W2048040403 hasAuthorship W2048040403A5032719662 @default.
• W2048040403 hasAuthorship W2048040403A5040967190 @default.
• W2048040403 hasAuthorship W2048040403A5070334233 @default.
• W2048040403 hasConcept C106773901 @default.
• W2048040403 hasConcept C108204754 @default.
• W2048040403 hasConcept C115624301 @default.
• W2048040403 hasConcept C155647269 @default.
• W2048040403 hasConcept C15920480 @default.
• W2048040403 hasConcept C161790260 @default.
• W2048040403 hasConcept C162862793 @default.
• W2048040403 hasConcept C178790620 @default.
• W2048040403 hasConcept C185592680 @default.
• W2048040403 hasConcept C188027245 @default.
• W2048040403 hasConcept C2777666793 @default.
• W2048040403 hasConcept C2777828636 @default.
• W2048040403 hasConcept C50027330 @default.
• W2048040403 hasConcept C521977710 @default.
• W2048040403 hasConcept C544153396 @default.
• W2048040403 hasConcept C68381374 @default.
• W2048040403 hasConcept C71240020 @default.
• W2048040403 hasConcept C8010536 @default.
• W2048040403 hasConceptScore W2048040403C106773901 @default.
• W2048040403 hasConceptScore W2048040403C108204754 @default.
• W2048040403 hasConceptScore W2048040403C115624301 @default.
• W2048040403 hasConceptScore W2048040403C155647269 @default.
• W2048040403 hasConceptScore W2048040403C15920480 @default.
• W2048040403 hasConceptScore W2048040403C161790260 @default.
• W2048040403 hasConceptScore W2048040403C162862793 @default.
• W2048040403 hasConceptScore W2048040403C178790620 @default.
• W2048040403 hasConceptScore W2048040403C185592680 @default.
• W2048040403 hasConceptScore W2048040403C188027245 @default.
• W2048040403 hasConceptScore W2048040403C2777666793 @default.
• W2048040403 hasConceptScore W2048040403C2777828636 @default.
• W2048040403 hasConceptScore W2048040403C50027330 @default.
• W2048040403 hasConceptScore W2048040403C521977710 @default.
• W2048040403 hasConceptScore W2048040403C544153396 @default.
• W2048040403 hasConceptScore W2048040403C68381374 @default.
• W2048040403 hasConceptScore W2048040403C71240020 @default.
• W2048040403 hasConceptScore W2048040403C8010536 @default.
• W2048040403 hasIssue "5" @default.
• W2048040403 hasLocation W20480404031 @default.
• W2048040403 hasOpenAccess W2048040403 @default.
• W2048040403 hasPrimaryLocation W20480404031 @default.
• W2048040403 hasRelatedWork W1983841738 @default.
• W2048040403 hasRelatedWork W1989347976 @default.
• W2048040403 hasRelatedWork W2019083207 @default.
• W2048040403 hasRelatedWork W2041013137 @default.
• W2048040403 hasRelatedWork W2069487452 @default.
• W2048040403 hasRelatedWork W2080922667 @default.

• next