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- W2048069007 abstract "Nanocrystal–graphene have been proposed as a new kind of promising hybrid for a wide range of application areas including catalysts, electronics, sensors, biomedicine, and energy storage, etc. Although a variety of methods have been developed for the preparation of hybrids, a facile and general synthetic approach is still highly required. In this study, nanocrystal–graphene hybrids were successfully synthesized in high-boiling-point organic solvents. Graphene oxide (GO) nanosheets were modified by oleylamine (OLA) to form a OLA–GO complex in order to be readily incorporated into hydrophobic synthesis. A rich library of highly crystalline nanocrystals, with types including noble metal, metal oxide, magnetic material and semiconductor were successfully grown on chemically converted graphene (CCG), which is simultaneously reduced from GO during the synthesis. High boiling-point solvents afford sufficient thermal energy to assure the high-quality crystalline nature of NCs, therefore the post-annealing process is obviated. Controlled experiments revealed that OLA–GO triggers heterogeneous nucleation and serves as excellent nuclei anchorage media. The protocol developed here brings one step closer to achieve “unity in diversity” on the preparation of nanocrystal–graphene hybrids." @default.
- W2048069007 created "2016-06-24" @default.
- W2048069007 creator A5026645245 @default.
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- W2048069007 creator A5085414120 @default.
- W2048069007 creator A5086561529 @default.
- W2048069007 creator A5089770860 @default.
- W2048069007 date "2012-01-01" @default.
- W2048069007 modified "2023-09-25" @default.
- W2048069007 title "Generalized syntheses of nanocrystal–graphene hybrids in high-boiling-point organic solvents" @default.
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- W2048069007 doi "https://doi.org/10.1039/c2nr30915g" @default.
- W2048069007 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22699842" @default.
- W2048069007 hasPublicationYear "2012" @default.
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