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- W2048072928 abstract "Abstract The vibration-rotation spectrum of the ν 2 and ν 5 fundamentals of CDF 3 have been recorded using a Nicolet 7199 Fourier transform infrared spectrometer; in addition the Q branch and several subbands of each of these transitions have been investigated using a tunable semiconductor diode laser spectrometer. The Q branch and the K structure in several P ( J ) and R ( J ) subbands of ν 2 , and in several Q branches of ν 5 , are resolved and assigned for the first time. Constants derived for these bands are (in cm −1 ) ν 2 = 1111.1823 6 , B 2 = 0.32928 2 , A 2 = 0.18872 2 , α 2 B = 16.44 5 × 10 −4 , α 2 B − α 2 A = 12.43 5 × 10 −4 , D 0 j = 3.7 3 × 10 −7 , D 2 J = 4.8 3 × 10 −7 ; ν 5 = 975.39 1 , B 5 = 0.33062, A 5 = 0.18887, α 5 B = 2.83 1 × 10 −4 , α 5 A = 2.4 3 × 10 −4 , ζ 5 = 0.736, D 5 J − D 0 J = 1.2 2 × 10 −8 . Some of these constants are nearly 100 times more precise than those reported in previous work." @default.
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- W2048072928 date "1981-10-01" @default.
- W2048072928 modified "2023-09-23" @default.
- W2048072928 title "High-resolution vibration-rotation spectroscopy of fluoroform-d" @default.
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- W2048072928 doi "https://doi.org/10.1016/0022-2852(81)90033-3" @default.
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