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- W2048101523 abstract "The electronic structure of Sr0.35CoO2, structurally analogous to the layered NaxCoO2, has been evaluated using the local spin density approximation (LSDA). We find that evident c-dispersions appear in both the e(g)' and a(1g) Co-derived bands, demonstrating the existence of a notable interplanar interaction in Sr0.35CoO2. The LSDA + U calculation reveals that the electronic structure, in particular the band splitting between the spin-up and spin-down electrons, changes evidently along with the increase of the effective on-site Coulomb interaction U. Analysis of theoretical and experimental electron energy-loss spectra (EELS) for the oxygen K-edge and the Co L-23-edge suggests that the on-site interaction (U) in Sr0.35CoO2 is less than 3 eV which is noticeably weaker than the estimated value (from 5 to 8 eV) in the NaxCoO2 materials. (C) 2005 Elsevier Ltd. All rights reserved." @default.
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- W2048101523 date "2005-09-01" @default.
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- W2048101523 title "Electronic structure and electron energy-loss spectra of Sr0.35CoO2" @default.
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- W2048101523 doi "https://doi.org/10.1016/j.ssc.2005.06.013" @default.
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