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- W2048152238 endingPage "4269" @default.
- W2048152238 startingPage "4261" @default.
- W2048152238 abstract "A series of disubstituted alkynylferrocenyl and -biferrocenyl ligands (1−4) have been synthesized and these then utilized to form a number of di-, tri-, and oligomeric platinum-containing alkynyl species (5−10). Characterization by spectroscopy and X-ray crystal structure determinations of [{C5H4FeC5H4C⋮CH}2] (3), [C6H5{(C2H5)3P}2PtC⋮CC5H4FeC5H4C⋮CPt{P(C2H5)3}2C6H5] (5), and [(C6H5Pt{P(C2H5)3}2C⋮C{C5H4Fe(C5H4)2FeC5H4}C⋮CPt{P(C2H5)3}2C6H5)] (8) illustrates their “rigid-rod” symmetrical geometries, featuring staggered cyclopentadienyl rings and almost perfect anti geometry of the ethynyl linkages in each case. Electrochemical and theoretical (extended Huckel calculations) studies on the metal complexes indicate that there is no metallocene−metallocene interaction through the alkynyl−platinum bridges." @default.
- W2048152238 created "2016-06-24" @default.
- W2048152238 creator A5000200207 @default.
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- W2048152238 date "1999-09-24" @default.
- W2048152238 modified "2023-10-10" @default.
- W2048152238 title "Synthesis, Characterization, and Theoretical Studies of New Alkynylferrocene and -biferrocene Ligands and Their Platinum-Containing Dimers and Oligomers" @default.
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- W2048152238 doi "https://doi.org/10.1021/om980986+" @default.
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