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- W2048154473 abstract "Isomerization of n-butane over several H-mordenite and Pd/H-mordenite samples with different Si/Al ratios is studied. 1,1,1,3,3,3-Hexamethyldisilazane was injected to obtain catalysts with poisoned external Brönsted acid sites. In the absence of metal, isomerization activity was virtually suppressed for the poisoned non-dealuminated mordenite catalysts. However, dealuminated samples were more resistant to the poisoning, and showed a higher selectivity to isobutane. For these samples, the reaction order with respect to n-butane was close to 1 for isobutane and close to 2 for pentanes, and turnover frequency (TOF) was not dependent on acid site density. No significant behaviour changes were observed for samples modified with Pd. It is proposed that isomerization of n-butane over the dealuminated samples can take place via monomolecular mechanism." @default.
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- W2048154473 date "2000-04-01" @default.
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- W2048154473 title "n-Butane isomerization over H-mordenite: role of the monomolecular mechanism" @default.
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- W2048154473 doi "https://doi.org/10.1016/s0926-860x(99)00477-9" @default.
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