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- W2048181288 abstract "Tricarbonyl-η 6 -N-carbethoxyazepine-metal(0) complexes of chromium, molybdenum and tungsten are formed, when tricarbonyl-trisacetonitrile-chromium(0), tricarbonyldiglyme-molybdenum(0) and tricarbonyl-trisacetonitrile-tungsten(0), respectively, are treated with N-carbethoxyazepine. According to the 1 H and 13 C NMR spectra of the N-carbethoxyazepine metal complexes two different ligand motions can be activated thermally. The carbethoxy group rotates around the C-N-bond (Δ G 300 ≠ = 64.6 to 66.1 kJ • mole -1 ) and the azepine ligand itself moves against the tricarbonyl metal groups (Δ G 250 ≠ 45.6-52.1 kJ • mole -1 )." @default.
- W2048181288 created "2016-06-24" @default.
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- W2048181288 date "1977-04-01" @default.
- W2048181288 modified "2023-10-17" @default.
- W2048181288 title "Gehinderte Ligandenbewegungen in Übergangsmetallkomplexen, XII<sup>1</sup> Tricarbonyl-η<sup>6</sup>-N-carbäthoxyazepin-chrom(0), -molybdän(0) und -wolfram(0) / Hindered Ligand Motions in Transition Metal Complexes, XII Tricarbonyl-η<sup>6</sup>-N-carbethoxyazepine-chromium(0), -molybdenum(0) and -tungsten(0)" @default.
- W2048181288 doi "https://doi.org/10.1515/znb-1977-0411" @default.
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