FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048186422> ?p ?o ?g. }

• W2048186422 endingPage "573" @default.
• W2048186422 startingPage "570" @default.
• W2048186422 abstract "Selective dechlorination of the chloromethyl-containing silanes (Cl3-nCHn)SiCl3-mMem (n = 0−2 (1−3), m = 0−3 (a−d)) with trichlorosilane was studied in the presence of group 10 transition-metal compounds at reaction temperatures between 100 and 150 °C in sealed bombs. The reactions give the corresponding less chlorinated compounds in good yields without reducing Si−Cl bonds, only when Pd(OAc)2 and PdCl2 were used as catalysts. The dechlorination rate of chlorinated methylchlorosilanes depends on the substituents on silicon and the number of chlorine atoms on the chlorinated carbon: the rate increases as the number of chlorine atoms on carbon and of methyl groups on silicon increase. The reactivity difference between (trichloromethyl)-, (dichloromethyl)-, and (monochloromethyl)chlorosilanes allows selective stepwise reduction from SiCCl3 to SiCHCl2 to SiCH2Cl and, finally, to SiCH3 by controlling the amount of trichlorosilane reductant and the reaction conditions. The catalytic reactivity of transition-metal compounds decreases in the following order: Pd(OAc)2 > PdCl2 >> Pt−C, H2PtCl6, Ni(OAc)2, NiCl2 > Pd(PPh3)2Cl2, K2PtCl4." @default.
• W2048186422 created "2016-06-24" @default.
• W2048186422 creator A5002292973 @default.
• W2048186422 creator A5042002197 @default.
• W2048186422 creator A5060160445 @default.
• W2048186422 creator A5079296386 @default.
• W2048186422 creator A5081666015 @default.
• W2048186422 date "1998-01-23" @default.
• W2048186422 modified "2023-10-18" @default.
• W2048186422 title "Palladium-Catalyzed Selective Dechlorination of Polychloromethylsilanes with Trichlorosilane" @default.
• W2048186422 cites W1593903784 @default.
• W2048186422 cites W1977161188 @default.
• W2048186422 cites W1980916034 @default.
• W2048186422 cites W1994619185 @default.
• W2048186422 cites W2019388960 @default.
• W2048186422 cites W2029923711 @default.
• W2048186422 cites W2040644730 @default.
• W2048186422 cites W2044984317 @default.
• W2048186422 cites W2050844955 @default.
• W2048186422 cites W2064824815 @default.
• W2048186422 cites W2067920643 @default.
• W2048186422 cites W2320122373 @default.
• W2048186422 cites W2322746046 @default.
• W2048186422 cites W2326688602 @default.
• W2048186422 cites W2334893357 @default.
• W2048186422 cites W2950321161 @default.
• W2048186422 cites W2951090402 @default.
• W2048186422 cites W2951135365 @default.
• W2048186422 cites W4243319540 @default.
• W2048186422 doi "https://doi.org/10.1021/om970490c" @default.
• W2048186422 hasPublicationYear "1998" @default.
• W2048186422 type Work @default.
• W2048186422 sameAs 2048186422 @default.
• W2048186422 citedByCount "11" @default.
• W2048186422 countsByYear W20481864222013 @default.
• W2048186422 countsByYear W20481864222022 @default.
• W2048186422 countsByYear W20481864222023 @default.
• W2048186422 crossrefType "journal-article" @default.
• W2048186422 hasAuthorship W2048186422A5002292973 @default.
• W2048186422 hasAuthorship W2048186422A5042002197 @default.
• W2048186422 hasAuthorship W2048186422A5060160445 @default.
• W2048186422 hasAuthorship W2048186422A5079296386 @default.
• W2048186422 hasAuthorship W2048186422A5081666015 @default.
• W2048186422 hasConcept C106773901 @default.
• W2048186422 hasConcept C142724271 @default.
• W2048186422 hasConcept C155647269 @default.
• W2048186422 hasConcept C157021035 @default.
• W2048186422 hasConcept C161790260 @default.
• W2048186422 hasConcept C178790620 @default.
• W2048186422 hasConcept C179104552 @default.
• W2048186422 hasConcept C185592680 @default.
• W2048186422 hasConcept C204787440 @default.
• W2048186422 hasConcept C2776910235 @default.
• W2048186422 hasConcept C2777166327 @default.
• W2048186422 hasConcept C2778024649 @default.
• W2048186422 hasConcept C2778183973 @default.
• W2048186422 hasConcept C2778815869 @default.
• W2048186422 hasConcept C2779248272 @default.
• W2048186422 hasConcept C502130503 @default.
• W2048186422 hasConcept C505241676 @default.
• W2048186422 hasConcept C544153396 @default.
• W2048186422 hasConcept C544956773 @default.
• W2048186422 hasConcept C71924100 @default.
• W2048186422 hasConcept C94882840 @default.
• W2048186422 hasConceptScore W2048186422C106773901 @default.
• W2048186422 hasConceptScore W2048186422C142724271 @default.
• W2048186422 hasConceptScore W2048186422C155647269 @default.
• W2048186422 hasConceptScore W2048186422C157021035 @default.
• W2048186422 hasConceptScore W2048186422C161790260 @default.
• W2048186422 hasConceptScore W2048186422C178790620 @default.
• W2048186422 hasConceptScore W2048186422C179104552 @default.
• W2048186422 hasConceptScore W2048186422C185592680 @default.
• W2048186422 hasConceptScore W2048186422C204787440 @default.
• W2048186422 hasConceptScore W2048186422C2776910235 @default.
• W2048186422 hasConceptScore W2048186422C2777166327 @default.
• W2048186422 hasConceptScore W2048186422C2778024649 @default.
• W2048186422 hasConceptScore W2048186422C2778183973 @default.
• W2048186422 hasConceptScore W2048186422C2778815869 @default.
• W2048186422 hasConceptScore W2048186422C2779248272 @default.
• W2048186422 hasConceptScore W2048186422C502130503 @default.
• W2048186422 hasConceptScore W2048186422C505241676 @default.
• W2048186422 hasConceptScore W2048186422C544153396 @default.
• W2048186422 hasConceptScore W2048186422C544956773 @default.
• W2048186422 hasConceptScore W2048186422C71924100 @default.
• W2048186422 hasConceptScore W2048186422C94882840 @default.
• W2048186422 hasIssue "4" @default.
• W2048186422 hasLocation W20481864221 @default.
• W2048186422 hasOpenAccess W2048186422 @default.
• W2048186422 hasPrimaryLocation W20481864221 @default.
• W2048186422 hasRelatedWork W2007720516 @default.
• W2048186422 hasRelatedWork W2020882448 @default.
• W2048186422 hasRelatedWork W2026695917 @default.
• W2048186422 hasRelatedWork W2048186422 @default.
• W2048186422 hasRelatedWork W2052684020 @default.
• W2048186422 hasRelatedWork W2052968075 @default.
• W2048186422 hasRelatedWork W2137465821 @default.
• W2048186422 hasRelatedWork W2321416729 @default.
• W2048186422 hasRelatedWork W2435148650 @default.

• next