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• W2048203496 abstract "A method for photochemical activation of glycosyl donors is presented. Selenoglycosides were activated by single-electron transfer using a photooxidant, N-methylquinolinium hexafluorophosphate, as photosensitizer and a toluene cosolvent as cosensitizer under irradiation at 350 nm. In this way we were able to synthesize glycosides including (1→6)-linked disaccharides. Benzyl ethers and benzoate esters were compatible with these conditions, allowing potentially synthetically useful transformations. The major by-products were due to hydrolysis; the reactions required the presence of oxygen and were run in air." @default.
• W2048203496 created "2016-06-24" @default.
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• W2048203496 date "2011-09-01" @default.
• W2048203496 modified "2023-09-25" @default.
• W2048203496 title "Photoinitiated Glycosylation at 350 nm" @default.
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• W2048203496 doi "https://doi.org/10.1080/07328303.2011.601533" @default.
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