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• W2048229162 abstract "In order to investigate the copper underpotential deposition (upd) on gold single crystals. X-ray surface diffraction (XRSD) measurements were performed under in-situ conditions. After formation of a complete Cu upd layer, Cu was found to adsorb in a commensurate p(1 × 1) structure in fourfold hollow sites with a vertical distance of 1.4 Å from the Au(100) surface. The coverage obtained by XRSD was (65 ± 8)%. The structure of the Cu upd layer was studied as a function of applied potential and of the Cu-ion concentration in solution. The Cu-ion concentration did not affect the structure of the Cu upd layer. As a function of the applied potential, it was possible to investigate the formation of the Cu upd layer by XRSD. From a comparison between the XRSD results and the cyclic voltammetry, the formation of an ionic adlayer is inferred for the Cu upd on Au(100) in perchloric acid." @default.
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• W2048229162 date "1997-10-01" @default.
• W2048229162 modified "2023-10-18" @default.
• W2048229162 title "In-situ X-ray surface diffraction of copper underpotential deposition on Au(100)" @default.
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• W2048229162 doi "https://doi.org/10.1016/s0022-0728(97)00339-2" @default.
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