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• W2048233204 abstract "[reaction: see text] Unusual palladium-catalyzed arylative fragmentations of acyclic 3-allen-1-ols were observed. Oxidative addition of Pd(0) to aryl halides would form the arylpalladium halides, which added to the central carbon of allenes via carbopalladation to form the pi-allylpalladium intermediates. The pi-allylpalladium intermediates would be reductively eliminated via carbon-carbon cleavage to give the arylated dienes and the alpha-hydroxyalkylpalladium intermediates, which were further reductively eliminated to the corresponding aldehydes." @default.
• W2048233204 created "2016-06-24" @default.
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• W2048233204 date "2002-08-22" @default.
• W2048233204 modified "2023-10-16" @default.
• W2048233204 title "Decarbopalladation of π-Allylpalladium Intermediates Formed from Palladium-Catalyzed Arylations of 3-Allen-1-ols" @default.
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• W2048233204 doi "https://doi.org/10.1021/ol026659m" @default.
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