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- W2048259743 abstract "The frequency, v, for O-D stretching in D2O films between the superimposed layers of different micas and montmorillonites was measured at several film thicknesses and temperatures of 2° and 25°C by infrared spectroscopy. The molar absorptivity, ε, for O-D stretching in HDO films between the mont-morillonite layers was also measured at different film thicknesses and 25°C. It was found that v is related to mw/mm, the mass ratio of D2O to mica or montmorillonite, by the equation v = v0 exp β/(mwmm where v0 is the O-D stretching frequency in pure D2O and ß is a constant. Since mw/mm is proportional to a, the area under the absorption peak, mw/mm can be replaced by a in this equation. It was also found that ε decreased dramatically as the thickness of the water film between the montmorillonite layers decreased. These results were interpreted to mean that the structure of the interlayer water is perturbed by the inter-layer cations and/or silicate surfaces." @default.
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- W2048259743 date "1980-01-01" @default.
- W2048259743 modified "2023-09-27" @default.
- W2048259743 title "Absorption of Infrared Radiation by D2O and HDO Mixed with Montmorillonite1" @default.
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- W2048259743 doi "https://doi.org/10.1346/ccmn.1980.0280206" @default.
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