Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048285877> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W2048285877 endingPage "1747" @default.
- W2048285877 startingPage "1747" @default.
- W2048285877 abstract "The nucleophilic attack of pin-2(10)-ene–mercury(II) complex systems by water results in the opening of the four-membered ring leading to an allylic organomercury(II) derivative (11) with the p-menthane skeleton. This intermediate can be reduced by hydride to p-menth-1 (2)-en-8-ol (6a) or can undergo an in situ SE2′ elimination yielding p-menth-1(7)-en-8-ol (9a), in high yields. (–)-2,10-Epoxypinane (15) reacts with mercury(II) salts at room temperature, giving the diol (16) in a quantitative yield. Compound (16) is a suitable intermediate for convenient preparation of p-mentha-1,8-dien-7-ol (17) and its derivatives." @default.
- W2048285877 created "2016-06-24" @default.
- W2048285877 creator A5025798874 @default.
- W2048285877 creator A5026445569 @default.
- W2048285877 creator A5040929067 @default.
- W2048285877 creator A5051012019 @default.
- W2048285877 date "1980-01-01" @default.
- W2048285877 modified "2023-09-23" @default.
- W2048285877 title "Cyclobutane ring opening of pin-2(10)-ene with mercury(II) salts. A new, high-yield synthesis of p-mentha-1,8-dien-7-ol" @default.
- W2048285877 doi "https://doi.org/10.1039/p19800001747" @default.
- W2048285877 hasPublicationYear "1980" @default.
- W2048285877 type Work @default.
- W2048285877 sameAs 2048285877 @default.
- W2048285877 citedByCount "11" @default.
- W2048285877 countsByYear W20482858772012 @default.
- W2048285877 countsByYear W20482858772018 @default.
- W2048285877 crossrefType "journal-article" @default.
- W2048285877 hasAuthorship W2048285877A5025798874 @default.
- W2048285877 hasAuthorship W2048285877A5026445569 @default.
- W2048285877 hasAuthorship W2048285877A5040929067 @default.
- W2048285877 hasAuthorship W2048285877A5051012019 @default.
- W2048285877 hasConcept C120095180 @default.
- W2048285877 hasConcept C134121241 @default.
- W2048285877 hasConcept C155647269 @default.
- W2048285877 hasConcept C161790260 @default.
- W2048285877 hasConcept C178790620 @default.
- W2048285877 hasConcept C178907741 @default.
- W2048285877 hasConcept C185592680 @default.
- W2048285877 hasConcept C191897082 @default.
- W2048285877 hasConcept C192562407 @default.
- W2048285877 hasConcept C199360897 @default.
- W2048285877 hasConcept C27777614 @default.
- W2048285877 hasConcept C2777777548 @default.
- W2048285877 hasConcept C2777961443 @default.
- W2048285877 hasConcept C2780377690 @default.
- W2048285877 hasConcept C2780378348 @default.
- W2048285877 hasConcept C41008148 @default.
- W2048285877 hasConcept C544153396 @default.
- W2048285877 hasConcept C71240020 @default.
- W2048285877 hasConceptScore W2048285877C120095180 @default.
- W2048285877 hasConceptScore W2048285877C134121241 @default.
- W2048285877 hasConceptScore W2048285877C155647269 @default.
- W2048285877 hasConceptScore W2048285877C161790260 @default.
- W2048285877 hasConceptScore W2048285877C178790620 @default.
- W2048285877 hasConceptScore W2048285877C178907741 @default.
- W2048285877 hasConceptScore W2048285877C185592680 @default.
- W2048285877 hasConceptScore W2048285877C191897082 @default.
- W2048285877 hasConceptScore W2048285877C192562407 @default.
- W2048285877 hasConceptScore W2048285877C199360897 @default.
- W2048285877 hasConceptScore W2048285877C27777614 @default.
- W2048285877 hasConceptScore W2048285877C2777777548 @default.
- W2048285877 hasConceptScore W2048285877C2777961443 @default.
- W2048285877 hasConceptScore W2048285877C2780377690 @default.
- W2048285877 hasConceptScore W2048285877C2780378348 @default.
- W2048285877 hasConceptScore W2048285877C41008148 @default.
- W2048285877 hasConceptScore W2048285877C544153396 @default.
- W2048285877 hasConceptScore W2048285877C71240020 @default.
- W2048285877 hasLocation W20482858771 @default.
- W2048285877 hasOpenAccess W2048285877 @default.
- W2048285877 hasPrimaryLocation W20482858771 @default.
- W2048285877 hasRelatedWork W2000319206 @default.
- W2048285877 hasRelatedWork W2007971536 @default.
- W2048285877 hasRelatedWork W2009844083 @default.
- W2048285877 hasRelatedWork W2088258719 @default.
- W2048285877 hasRelatedWork W2097014657 @default.
- W2048285877 hasRelatedWork W2162041534 @default.
- W2048285877 hasRelatedWork W2398501682 @default.
- W2048285877 hasRelatedWork W2950054151 @default.
- W2048285877 hasRelatedWork W4239384447 @default.
- W2048285877 hasRelatedWork W4255845432 @default.
- W2048285877 isParatext "false" @default.
- W2048285877 isRetracted "false" @default.
- W2048285877 magId "2048285877" @default.
- W2048285877 workType "article" @default.