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- W2048286211 abstract "Three different conversion and refining methods for the preparation of high purity plutonium metal are described: the calciothermic reduction of plutonium oxide followed by electrorefining; the thoriothermic reduction of plutonium oxide followed by selective evaporation; the tantalothermic reduction of plutonium carbide followed by selective evaporation. The calciothermic reduction of plutonium oxide followed by electrorefining is used for the semi-industrial or large scale production of high purity plutonium metal. The rate and yield of preparation and refining is high. With high purity reactants the reduction of the oxide with thorium is well adapted to obtain high purity plutonium metal on the laboratory scale. The tantalothermic reduction of plutonium carbide gives high purity plutonium metal even with impure plutonium starting material (recovered from waste). This results from the high selectivity at the different steps of the process." @default.
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- W2048286211 date "1985-06-01" @default.
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- W2048286211 title "Direct reduction of actinide oxide and carbide to metal: Application to the preparation of plutonium metal" @default.
- W2048286211 doi "https://doi.org/10.1016/0168-9002(85)90949-0" @default.
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