FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2048291344> ?p ?o ?g. }

• W2048291344 endingPage "659" @default.
• W2048291344 startingPage "653" @default.
• W2048291344 abstract "Three molecularly imprinted polymers (MIPs) were prepared using the phytohormone indole-3-acetic acid (IAA) as a template molecule, 4-vinylpyridine (MIP-1 and MIP-2) or N,N-dimethylaminoethyl methacrylate (MIP-3) as functional monomers, ethylenglycol dimethacrylate as a cross linker and acetonitrile (MIP-1), a methanol–water mixture (MIP-2) or chloroform (MIP-3) as porogens. Retention factors for IAA and 29 indole derivatives were determined by high-performance liquid chromatography, using the molecularly imprinted polymers as stationary phases and acetonitrile as an eluent. High correlations between selectivity factors of above mentioned polymers indicate that their retention mechanisms are basically the same. A quantitative structure–property relationships analysis revealed that the presence of the terminal carboxyl group on the 3-side chain plays an essential role in the binding of the indole derivatives to the polymers. The derivatives without the carboxyl group exhibit a drastically lower affinity toward the polymers. Another factor which favors the binding is electronic density of indole nucleus. Substituents with electro-withdrawing properties enhance the binding, while electro-donating substituents have the opposite effect. The length of the 3-side chain also affects the binding. Indole-3-carboxylic acid having the carboxyl group directly attached to the ring as well as the derivatives whose side chain is longer than that of IAA bind to the polymers with a lower affinity." @default.
• W2048291344 created "2016-06-24" @default.
• W2048291344 creator A5043570161 @default.
• W2048291344 creator A5065276434 @default.
• W2048291344 creator A5073587941 @default.
• W2048291344 date "2013-02-01" @default.
• W2048291344 modified "2023-10-18" @default.
• W2048291344 title "Molecular recognition of indole derivatives by polymers imprinted with indole-3-acetic acid: A QSPR study" @default.
• W2048291344 cites W1965418999 @default.
• W2048291344 cites W1970372654 @default.
• W2048291344 cites W1972633502 @default.
• W2048291344 cites W1973453874 @default.
• W2048291344 cites W1978788662 @default.
• W2048291344 cites W1987089554 @default.
• W2048291344 cites W2004645846 @default.
• W2048291344 cites W2014372920 @default.
• W2048291344 cites W2024460170 @default.
• W2048291344 cites W2024700582 @default.
• W2048291344 cites W2031199055 @default.
• W2048291344 cites W2039406414 @default.
• W2048291344 cites W2049656920 @default.
• W2048291344 cites W2054716083 @default.
• W2048291344 cites W2069216251 @default.
• W2048291344 cites W2074681440 @default.
• W2048291344 cites W2078408921 @default.
• W2048291344 cites W2088304248 @default.
• W2048291344 cites W2092493119 @default.
• W2048291344 cites W2152832652 @default.
• W2048291344 cites W2160648204 @default.
• W2048291344 cites W2163472296 @default.
• W2048291344 doi "https://doi.org/10.1016/j.bmc.2012.11.048" @default.
• W2048291344 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23290253" @default.
• W2048291344 hasPublicationYear "2013" @default.
• W2048291344 type Work @default.
• W2048291344 sameAs 2048291344 @default.
• W2048291344 citedByCount "13" @default.
• W2048291344 countsByYear W20482913442013 @default.
• W2048291344 countsByYear W20482913442014 @default.
• W2048291344 countsByYear W20482913442015 @default.
• W2048291344 countsByYear W20482913442016 @default.
• W2048291344 countsByYear W20482913442017 @default.
• W2048291344 countsByYear W20482913442018 @default.
• W2048291344 countsByYear W20482913442019 @default.
• W2048291344 countsByYear W20482913442023 @default.
• W2048291344 crossrefType "journal-article" @default.
• W2048291344 hasAuthorship W2048291344A5043570161 @default.
• W2048291344 hasAuthorship W2048291344A5065276434 @default.
• W2048291344 hasAuthorship W2048291344A5073587941 @default.
• W2048291344 hasConcept C104317684 @default.
• W2048291344 hasConcept C111919701 @default.
• W2048291344 hasConcept C118792377 @default.
• W2048291344 hasConcept C132050475 @default.
• W2048291344 hasConcept C161790260 @default.
• W2048291344 hasConcept C162602672 @default.
• W2048291344 hasConcept C166940927 @default.
• W2048291344 hasConcept C178790620 @default.
• W2048291344 hasConcept C185592680 @default.
• W2048291344 hasConcept C188027245 @default.
• W2048291344 hasConcept C192527728 @default.
• W2048291344 hasConcept C204921945 @default.
• W2048291344 hasConcept C207778908 @default.
• W2048291344 hasConcept C21951064 @default.
• W2048291344 hasConcept C2777463227 @default.
• W2048291344 hasConcept C2778707554 @default.
• W2048291344 hasConcept C2780557392 @default.
• W2048291344 hasConcept C41008148 @default.
• W2048291344 hasConcept C521977710 @default.
• W2048291344 hasConcept C55493867 @default.
• W2048291344 hasConceptScore W2048291344C104317684 @default.
• W2048291344 hasConceptScore W2048291344C111919701 @default.
• W2048291344 hasConceptScore W2048291344C118792377 @default.
• W2048291344 hasConceptScore W2048291344C132050475 @default.
• W2048291344 hasConceptScore W2048291344C161790260 @default.
• W2048291344 hasConceptScore W2048291344C162602672 @default.
• W2048291344 hasConceptScore W2048291344C166940927 @default.
• W2048291344 hasConceptScore W2048291344C178790620 @default.
• W2048291344 hasConceptScore W2048291344C185592680 @default.
• W2048291344 hasConceptScore W2048291344C188027245 @default.
• W2048291344 hasConceptScore W2048291344C192527728 @default.
• W2048291344 hasConceptScore W2048291344C204921945 @default.
• W2048291344 hasConceptScore W2048291344C207778908 @default.
• W2048291344 hasConceptScore W2048291344C21951064 @default.
• W2048291344 hasConceptScore W2048291344C2777463227 @default.
• W2048291344 hasConceptScore W2048291344C2778707554 @default.
• W2048291344 hasConceptScore W2048291344C2780557392 @default.
• W2048291344 hasConceptScore W2048291344C41008148 @default.
• W2048291344 hasConceptScore W2048291344C521977710 @default.
• W2048291344 hasConceptScore W2048291344C55493867 @default.
• W2048291344 hasIssue "3" @default.
• W2048291344 hasLocation W20482913441 @default.
• W2048291344 hasLocation W20482913442 @default.
• W2048291344 hasOpenAccess W2048291344 @default.
• W2048291344 hasPrimaryLocation W20482913441 @default.
• W2048291344 hasRelatedWork W1970372654 @default.
• W2048291344 hasRelatedWork W2004299422 @default.
• W2048291344 hasRelatedWork W2012633673 @default.
• W2048291344 hasRelatedWork W2040358405 @default.
• W2048291344 hasRelatedWork W2041523100 @default.

• next