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- W2048291657 abstract "Various adiabatic mixing schemes are explored using numerical simulations with the aim of finding suitable mixing sequences for fast rotating samples with relatively wide resonances and poorly resolved J-couplings, such as proteins or resin-bound products of solid-phase synthesis. It is shown both experimentally and by simulations that WURST-2 mixing scheme provides the best sensitivity and the lowest interference from cross-relaxation effects in the spin diffusion limit. For medium-sized molecules, WURST-1, constant adiabaticity Gaussian and hyperbolic secant are the possible alternatives. Copyright © 2001 John Wiley & Sons, Ltd." @default.
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- W2048291657 date "2001-01-01" @default.
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- W2048291657 title "Clean adiabatic TOCSYs" @default.
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- W2048291657 doi "https://doi.org/10.1002/mrc.831" @default.
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