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- W2048293003 abstract "[1.1]Ferrocenophane (1) has been shown to catalyze the photochemical splitting of water and iron diprotonated [1.1]ferrocenophane has been postulated as a reactive intermediate in this process. However, it has previously not been possible to observe the species directly by, e.g., NMR spectroscopy, since under the conditions it rapidly eliminates hydrogen. By employing a special ion generation technique, 1 has been pronated in superacid (FSO3H–SO2CIF) at −125°C. Under these conditions, the cation formed has a long lifetime and its structure and dynamics have been studied by NMR spectroscopy. The ion observed is iron diprotonated [1.1]ferrocenophane (2), which undergoes rapid degenerate rearrangements. 1H1H NOESY experiments suggest that in 2 the cyclopentadienyl rings in the ferrocene units are tilted relative to each other. © 1997 John Wiley & Sons, Ltd." @default.
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- W2048293003 date "1997-07-01" @default.
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- W2048293003 title "Iron diprotonated [1.1] ferrocenophane generated in super-acid and directly observed by NMR spectroscopy" @default.
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- W2048293003 doi "https://doi.org/10.1002/(sici)1099-1395(199707)10:7<590::aid-poc919>3.0.co;2-m" @default.
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