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• W2048301314 startingPage "1587" @default.
• W2048301314 abstract "Doping of polyaniline with a new family of protonating agents, namely sulfosuccinates with alkyl or alkoxy substituents, is discussed. The resulting polyaniline-sulfosuccinates exhibit a lamellar type structural organization in which stacks of polymer chains are separated by dopant anions. Although structurally similar to previously studied polyaniline-sulfophthalates, polyaniline-sulfosuccinates are better ordered and exhibit better physical properties. In particular, they exhibit metallic-type conductivity down to 210 K and they can be stretched at room temperature to elongations at break, Δl/lo, approaching 200%. Mechanical stretching does not affect the temperature range of the metallic conductivity, however, it does induce a 4-fold increase in the room-temperature conductivity of the polymer. Low Tg of polyaniline-sulfosuccinates is also the origin of the low temperature thermochromism a phenomenon reported so far only for polyaniline-sulfosuccinates and polyaniline-sulfophthalates. Finally, accelerated aging tests carried out at a temperature of 408 K, in ambient conditions, have shown that polyaniline doped with di-(2-butoxyethyl) ester of sulfosuccinic acid is thermally more stable than poly(3,4-ethylenedioxythiophene) doped with ferric tosylate (FeIII(Tos)3) the system considered so far as the most stable of all conducting polymers." @default.
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• W2048301314 date "2003-03-26" @default.
• W2048301314 modified "2023-10-16" @default.
• W2048301314 title "Low <i>T</i>_g, Stretchable Polyaniline of Metallic-Type Conductivity: Role of Dopant Engineering in the Control of Polymer Supramolecular Organization and in the Tuning of Its Properties" @default.
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• W2048301314 doi "https://doi.org/10.1021/cm021354n" @default.
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