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- W2048340904 abstract "Abstract The effect of some parameters, i.e. temperature, time, pH and concentration, on the baker's yeast reduction of ethyl 4,4,4-trifluoroacetoacetate is presented. The enantiomeric excess of the R enantiomer appeared to increase up to 76% when the temperature of the reduction decreased. The other factors do not appear to improve the enantioselectivity of the reaction. Reduction with Candida utilis allowed preparation of the S enantiomer in higher optical purity than previously reported." @default.
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- W2048340904 date "1991-01-01" @default.
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- W2048340904 title "Preparation of both enantiomers of ethyl 4,4,4-trifluoro-3-hydroxy butanoate by enantioselective microbial reduction" @default.
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- W2048340904 doi "https://doi.org/10.1016/s0960-894x(01)81046-5" @default.
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