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• W2048345038 startingPage "288" @default.
• W2048345038 abstract "The methanol electro-oxidation (MEO) on Pd–SnO2/MWCNTs catalysts prepared by microwave-assisted polyol reduction method has been investigated. The structure, morphology and electro-catalytic performances of the catalysts were characterized with XRD, TEM and cyclic voltammetry (CV). The results showed that the highly dispersed Pd nano-particles (PdNPs) with a narrow size distribution on MWCNTs were successfully synthesized. The catalytic activity of Pd–SnO2/MWCNTs for MEO was up to 778.8 mA/mg Pd in 0.1 M KOH solution containing 1 M methanol, which was significant higher than that of Pd/C (414.2 mA/mg Pd) or Pd–SnO2/C (566.7 mA/mg Pd). Moreover, the MEO on Pd–SnO2/MWCNTs electrode displayed an irreversible behavior under a diffusion control giving an exchange current density (j0) of 3.76 × 10−4 A cm−2 and a Tafel slope of 149 mV dec−1 (α = 0.56) at 25 °C, which indicates that Pd–SnO2/MWCNTs catalyst has a high electro-catalytic performance for the MEO in alkaline media." @default.
• W2048345038 created "2016-06-24" @default.
• W2048345038 creator A5067736547 @default.
• W2048345038 creator A5080788081 @default.
• W2048345038 creator A5090482992 @default.
• W2048345038 date "2014-01-01" @default.
• W2048345038 modified "2023-10-18" @default.
• W2048345038 title "Electro-oxidation of methanol on SnO2-promoted Pd/MWCNTs catalysts in alkaline solution" @default.
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• W2048345038 doi "https://doi.org/10.1016/j.ijhydene.2013.10.012" @default.
• W2048345038 hasPublicationYear "2014" @default.
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