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- W2048444081 abstract "A convenient method for the preparation of transition metal complexes of L-tyrosine (tyrH) is reported and this has enabled eight complexes of the tyrosinate anion (tyr) to be prepared: M(tyr)2(H2On (M = Co, Ni, Cu, Zn; n = 1, 2, 3), [Cu(tyr)(NO3)], and Li[Cu(tyr)3]. Electronic spectra and magnetic measurements imply that the nickel(II) complex contains the N2O4 donor set, and the similarity of the infrared spectra of the other bistyrosinate complexes to the nickel derivative suggests a similar six-coordinate structure. Experiment suggests that upon reacting Lityr with copper(II) nitrate in water the green kinetic product [Cu(tyr)(NO3)] forms, but on standing this changes to the thermodynamically stable product, [Cu(tyr)2]." @default.
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- W2048444081 date "1973-01-01" @default.
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- W2048444081 title "Metal complexes of amino acids and derivatives. V. The donor properties of L-tyrosine" @default.
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- W2048444081 doi "https://doi.org/10.1016/s0020-1693(00)94806-0" @default.
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