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• W2048444134 abstract "This paper describes a systematic study on the thermal polymerization of both pristine 4-vinylbenzenesulfonic anion (VBS) and intercalated VBS in the two-dimensional (2D) gallery of Ni-Al layered double hydroxide (VBS/Ni-Al-LDH), by virtue of combining experimental and theoretical investigations. In situ FT-IR, in situ high-temperature X-ray diffraction (HT-XRD), UV-vis absorption spectroscopy, TG-DTA and elemental analysis were used to study the polymerization process, and it was found that the polymerization of VBS/Ni-Al-LDH occurs at ca. 150-170 degrees C, at least 40 degrees C lower than that of the pristine VBS, indicating that the layered structure of LDH is favorable for thermal polymerization of VBS. Therefore, this layered inorganic material may have potential application as a molecular reactor for enhancing the efficiency of polymerization reaction. Furthermore, the sheet-like polymerization product was obtained with the LDHs lamella as template. For better understanding the structure and arrangement of intercalated VBS and the polymerization product between the layers of Ni-Al-LDH, molecular dynamics (MD) simulation method was employed. The simulation results of hydration energies show that there are two relatively stable stages upon the increase of the number of interlayer water molecules. VBS molecules exhibit a tendency from tilted to vertical orientation with respect to the layers as the interlayer water content increases. Compared with the experimental results, the calculated interlayer spacing is more severely affected by interlayer water content. Finally, a typical tetramer product of VBS intercalated LDH was studied and the simulated equilibrium interlayer spacing is consistent with the experimental result of in situ HT-XRD. Based on the combination of experimental and theoretical studies on the interlayer polymerization system, the aim of this work is to deeply investigate the differences in thermal polymerization process between pristine monomers and intercalated ones in the gallery of LDHs, and to give detailed information of the arrangement and swelling behavior of guest molecules confined between the sheets of host layers." @default.
• W2048444134 created "2016-06-24" @default.
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• W2048444134 date "2008-07-25" @default.
• W2048444134 modified "2023-09-26" @default.
• W2048444134 title "In Situ Polymerization of the 4-Vinylbenzenesulfonic Anion in Ni−Al−Layered Double Hydroxide and Its Molecular Dynamic Simulation" @default.
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• W2048444134 doi "https://doi.org/10.1021/jp801922b" @default.
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